New Ag8PtO6: synthesis, crystal structure, physical properties and theoretical analyses
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Thakur, Gohil Singh | |
dc.contributor.author | Reuter, Hans | |
dc.contributor.author | Rosner, Helge | |
dc.contributor.author | Fecher, Gerhard H. | |
dc.contributor.author | Felser, Claudia | |
dc.contributor.author | Jansen, Martin | |
dc.date.accessioned | 2021-12-23T16:13:40Z | - |
dc.date.available | 2021-12-23T16:13:40Z | - |
dc.date.issued | 2019 | |
dc.identifier.issn | 14779226 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/10685 | - |
dc.description.abstract | We report the synthesis, crystal structure, and basic physical properties of Ag8PtO6, which represents the first silver platinum ternary oxide. The crystalline compound was obtained from appropriate mixtures of the binary constituents under alkaline conditions at high oxygen pressure, while applying relatively mild thermal conditions (573 K). Ag8PtO6 crystallizes in a new crystal structure in the triclinic system (P1). The structure consists of slightly distorted, discrete PtO6 octahedra, which are linked via O-Ag-O dumbbells to form a three dimensional framework. It is a diamagnetic semiconductor with a band gap of 0.9 eV. DFT based calculations confirm an electronic ground state that corresponds to a 5d(6) 6s(0) configuration of the Pt atoms, in accordance with the observed diamagnetism. | |
dc.description.sponsorship | Max Planck SocietyMax Planck SocietyFoundation CELLEX; The authors thank Dr Walter Schnelle and Dr Reinhard Kremer for the magnetic measurements. Open Access funding provided by the Max Planck Society. | |
dc.language.iso | en | |
dc.publisher | ROYAL SOC CHEMISTRY | |
dc.relation.ispartof | DALTON TRANSACTIONS | |
dc.subject | Chemistry | |
dc.subject | Chemistry, Inorganic & Nuclear | |
dc.subject | ORBITAL PHYSICS | |
dc.title | New Ag8PtO6: synthesis, crystal structure, physical properties and theoretical analyses | |
dc.type | journal article | |
dc.identifier.doi | 10.1039/c8dt05081c | |
dc.identifier.isi | ISI:000468001400030 | |
dc.description.volume | 48 | |
dc.description.issue | 15 | |
dc.description.startpage | 5058 | |
dc.description.endpage | 5063 | |
dc.contributor.orcid | 0000-0002-8200-2063 | |
dc.contributor.orcid | 0000-0002-9884-1291 | |
dc.contributor.orcid | 0000-0002-1362-2357 | |
dc.contributor.researcherid | AAC-2642-2021 | |
dc.contributor.researcherid | A-5779-2009 | |
dc.contributor.researcherid | P-4500-2016 | |
dc.identifier.eissn | 14779234 | |
dc.publisher.place | THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND | |
dcterms.isPartOf.abbreviation | Dalton Trans. | |
dcterms.oaStatus | Green Submitted, hybrid | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | ReHa636 | - |
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geprüft am 01.06.2024