Influence of alpha-Fe2O3 nanorods on the thermal stability of poly(methyl methacrylate) synthesized by in situ bulk polymerisation of methyl methacrylate

DC FieldValueLanguage
dc.contributor.authorDzunuzovic, E.
dc.contributor.authorMarinovic-Cincovic, M.
dc.contributor.authorJeremic, K.
dc.contributor.authorVukovic, J.
dc.contributor.authorNedeljkovic, J.
dc.date.accessioned2021-12-23T16:13:55Z-
dc.date.available2021-12-23T16:13:55Z-
dc.date.issued2008
dc.identifier.issn01413910
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/10814-
dc.description.abstractalpha-Fe2O3 nanorods were incorporated into poly(methyl methacrylate) (PMMA) by in situ radical polymerisation of methyl methacrylate initiated by 2,2 `-azobisisobutyronitrile. The alpha-Fe2O3 nanorods were synthesized by forced hydrolysis of FeCl3 and structural characterization was performed by X-ray diffraction and transmission electron microscopy. The molar mass and the polydispersity index of synthesized PMMA samples were determined by gel permeation chromatography. The content of residual monomer was determined by H-1 NMR spectroscopy. The influence of alpha-Fe2O3 nanorods on the thermal stability of the polymer was investigated using thermogravimetry and differential scanning calorimetry. The molar mass and polydispersity index of PMMA were dependent on the content of alpha-Fe2O3 nanorods. The values of the glass transition temperature of the nanocomposites were lower compared to pure PMMA. Also, the thermal stability of nanocomposites in nitrogen and air was different from that of pure PMMA. (c) 2007 Elsevier Ltd. All rights reserved.
dc.language.isoen
dc.publisherELSEVIER SCI LTD
dc.relation.ispartofPOLYMER DEGRADATION AND STABILITY
dc.subjectalpha-Fe2O3 nanorods
dc.subjectBEHAVIOR
dc.subjectbulk radical polymerisation
dc.subjectFILLERS
dc.subjectnanocomposite
dc.subjectNANOCOMPOSITES
dc.subjectNANOPARTICLES
dc.subjectOXIDATIVE-DEGRADATION
dc.subjectPARTICLES
dc.subjectPMMA
dc.subjectPolymer Science
dc.subjectPOLYMERS
dc.subjectPOLYSTYRENE
dc.subjectSEMICONDUCTORS
dc.subjectWEIGHT
dc.titleInfluence of alpha-Fe2O3 nanorods on the thermal stability of poly(methyl methacrylate) synthesized by in situ bulk polymerisation of methyl methacrylate
dc.typejournal article
dc.identifier.doi10.1016/j.polymdegradstab.2007.10.015
dc.identifier.isiISI:000253305500010
dc.description.volume93
dc.description.issue1
dc.description.startpage77
dc.description.endpage83
dc.contributor.orcid0000-0001-6197-1511
dc.contributor.researcheridD-4202-2017
dc.publisher.placeTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND
dcterms.isPartOf.abbreviationPolym. Degrad. Stabil.
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