Dynamics of light-induced NIR-absorption of Nb4+ polarons in SBN : Cr crystals at low temperature

Autor(en): Gao, M
Vikhnin, V
Kapphan, S
Stichwörter: Cr3+/4+-centers; light-induced absorption; non-monoexponential decay; Nuclear Science & Technology; Physics; Physics, Condensed Matter; Physics, Fluids & Plasmas; polarons; Sr(x)Ba(1-x)Nb(2)Or(6) (SBN)
Erscheinungsdatum: 1999
Herausgeber: GORDON BREACH SCI PUBL LTD
Journal: RADIATION EFFECTS AND DEFECTS IN SOLIDS
Volumen: 151
Ausgabe: 1-4
Startseite: 51
Seitenende: 55
Zusammenfassung: 
The dynamics of light-induced (Kr+, Ar+-laser) electronic polarons (Nb4+ centers with broad absorption band around 0.8 eV) and light-induced centers of other types were investigated in SrxBa1-xNb2O6:Cr (SBN:Cr) and in SBN:Ce using FTIR absorption measurements at low temperature. A theoretical model involving Cr3+/Ca4+, Ce3+/Ce4+ Nb4+ electronic polarons and trapping X-centers is proposed. The trapping of polarons at Cr4+/Ce4+ centers with subsequent recharging is shown to play an important role in the polaron dynamics. The predictions of the model are in very good agreement with the experimental results.
Beschreibung: 
8th Europhysical Conference on Defects in Insulating Materials (EURODIM98), UNIV KEELE, KEELE, ENGLAND, JUL 06-11, 1998
ISSN: 10420150
DOI: 10.1080/10420159908245936

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