Synthesis of new paramagnetic fatty acids and lipophilic spin labels
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Balog, Maria | |
dc.contributor.author | Abe, Christoph | |
dc.contributor.author | Kalai, Tamas | |
dc.contributor.author | Steinhoff, Heinz-Juergen | |
dc.contributor.author | Jeko, Jozsef | |
dc.contributor.author | Hideg, Kalman | |
dc.date.accessioned | 2021-12-23T16:15:16Z | - |
dc.date.available | 2021-12-23T16:15:16Z | - |
dc.date.issued | 2007 | |
dc.identifier.issn | 00397881 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/11358 | - |
dc.description.abstract | Starting from readily available five-membered cyclic nitrones, paramagnetic analogues of palmitic and hexadec-2E-enoic acids are described with a range of pyrrolidine ring orientations. Herein we report the synthesis of 3,4-disubstituted lipophilic pyrroline nitroxides through a palladium-catalyzed cross-coupling reaction. Lipophilic phosphonium salt and SH-specific labels (methanethiosulfonates and isoselenuronium salts) with allylic and propargylic terminal groups are also described. | |
dc.language.iso | en | |
dc.publisher | GEORG THIEME VERLAG KG | |
dc.relation.ispartof | SYNTHESIS-STUTTGART | |
dc.subject | Chemistry | |
dc.subject | Chemistry, Organic | |
dc.subject | CROSS-COUPLING REACTIONS | |
dc.subject | DERIVATIVES | |
dc.subject | EPR | |
dc.subject | fatty acids | |
dc.subject | free radicals | |
dc.subject | Grignard reaction | |
dc.subject | lipids | |
dc.subject | MITOCHONDRIA | |
dc.subject | NITROXYLS | |
dc.subject | palladium-catalyzed reactions | |
dc.subject | PEROXIDE | |
dc.subject | PHOSPHOLIPID-BILAYERS | |
dc.subject | RADICALS | |
dc.subject | SPECTROSCOPY | |
dc.subject | VERSATILE | |
dc.title | Synthesis of new paramagnetic fatty acids and lipophilic spin labels | |
dc.type | journal article | |
dc.identifier.doi | 10.1055/s-2007-966067 | |
dc.identifier.isi | ISI:000247311100010 | |
dc.description.issue | 11 | |
dc.description.startpage | 1663 | |
dc.description.endpage | 1670 | |
dc.contributor.orcid | 0000-0002-5888-0157 | |
dc.contributor.orcid | 0000-0002-1680-8480 | |
dc.contributor.researcherid | H-3791-2014 | |
dc.publisher.place | RUDIGERSTR 14, D-70469 STUTTGART, GERMANY | |
dcterms.isPartOf.abbreviation | Synthesis | |
crisitem.author.dept | FB 04 - Physik | - |
crisitem.author.deptid | fb04 | - |
crisitem.author.parentorg | Universität Osnabrück | - |
crisitem.author.netid | StHe633 | - |
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geprüft am 06.06.2024