Photo dissociation of blue-light-induced VIS-centers in SBN : Ce, Cr and in BCT : Fe into small polarons at low temperatures
Autor(en): | Kapphan, S Gubaev, A Kislova, I Kutsenko, A Pankrath, R Vikhnin, V |
Stichwörter: | ABSORPTION; barium-calcium titanate (BCT); CRYSTALS; light-induced absorption; Materials Science; Materials Science, Multidisciplinary; photo-dissociation; PHOTOREFRACTIVE PROPERTIES; Physics; Physics, Condensed Matter; small polarons; STRONTIUM-BARIUM NIOBATE; strontium-barium niobate (SBN) | Erscheinungsdatum: | 2004 | Herausgeber: | TAYLOR & FRANCIS LTD | Enthalten in: | FERROELECTRICS | Band: | 303 | Startseite: | 107 | Seitenende: | 112 | Zusammenfassung: | The promising photorefractive single crystal systems Sr(x)Ba(1-x)N(b)2O(6) (SBN, congruent composition x = 0.61) [1] and Ba1-yCayTiO3 (BCT, congruent y = 0.23) [2], can be doped with polyvalent ions like Fe, Cr, Cc to enhance and optimize their photorefractive properties. Illumination with blue Ar+-laser light at low temperature creates light-induced NIR and VIS absorption bands [3, 4]. The NIR absorption has been identified as being due to electron polarons (Nb4+ in SBN, Ti3+ in BCT) and their properties have been investigated in some detail [3, 4]. The VIS-Centers (at about 2 eV) are less well understood and their nature is still under discussion [5]. We could show that illumination with red Kr+-laser light (647 nm) leads to a dissociation of the VIS-Centers and a simultaneous build-up of a transient NIR-polaron absorption [5]. These features give new insight into the dynamic nature of these VIS-Centers. |
Beschreibung: | 10th European Meeting on Ferroelectricity, Univ Cambridge, Cambridge, ENGLAND, AUG 03-08, 2003 |
ISSN: | 00150193 | DOI: | 10.1080/00150190490452866 |
Zur Langanzeige
Seitenaufrufe
1
Letzte Woche
0
0
Letzter Monat
0
0
geprüft am 09.06.2024