Evidence of four light-induced metastable states in iron-nitrosyl complexes

Autor(en): Schaniel, D
Woike, T
Tsankov, L
Imlau, M 
Stichwörter: Chemistry; Chemistry, Analytical; Chemistry, Physical; COORDINATION; CRYSTALS; differential scanning calorimetry; enthalpy; EXISTENCE; LINKAGE ISOMERS; metastable states; POPULATION; SODIUMNITROPRUSSIDE; SPECTRA; STRUCTURAL-CHANGES; Thermodynamics; TRANSITION-METAL NITROSYL
Erscheinungsdatum: 2005
Herausgeber: ELSEVIER
Enthalten in: THERMOCHIMICA ACTA
Band: 429
Ausgabe: 1
Startseite: 19
Seitenende: 23
Zusammenfassung: 
Thermodynamic measurements on irradiated Na-2[Fe(CN)(5)NO]center dot 2H(2)O reveal the existence of four light-induced long-lived metastable states, which decay exponentially in time. The activation energies and frequency factors of the four independent states are determined from isothermal calorimetric and differential scanning calorimetric measurements. (c) 2004 Elsevier B.V. All rights reserved.
ISSN: 00406031
DOI: 10.1016/j.tca.2004.11.024

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