X-ray Absorption and Photoelectron Characterization of Carbon Shell Extracted from Ni@C Nanoparticles
Autor(en): | Galakhov, V. R. Shamin, S. N. Mesilov, V. V. Ovechkina, N. A. Uimin, M. A. Yermakov, A. Ye. Schneider, L. Balinski, K. Senkovskiy, B. V. |
Stichwörter: | Chemistry; Chemistry, Physical; EDGE; EMISSION; FINE-STRUCTURE; GROWTH; Materials Science; Materials Science, Multidisciplinary; NANOCRYSTALS; Nanoscience & Nanotechnology; NANOTUBES; NICKEL; PALLADIUM; Science & Technology - Other Topics; SPECTRA; SPECTROSCOPY | Erscheinungsdatum: | 2014 | Herausgeber: | AMER CHEMICAL SOC | Journal: | JOURNAL OF PHYSICAL CHEMISTRY C | Volumen: | 118 | Ausgabe: | 51 | Startseite: | 30216 | Seitenende: | 30220 | Zusammenfassung: | Ni@C nanocomposites and the carbon shells extracted by etching Ni@C in nitric acid have been characterized by means of soft X-ray absorption and X-ray photoelectron spectroscopies. It was found on the base of Ni 2p X-ray absorption spectra and atomic multiplet calculations that Ni traces in the carbon-shell sample are in the Ni2+ state formed probably by nickel nitrate hexahydrate, Ni(NO3)(2)6H(2)O. Second derivatives of C 1s of X-ray absorption spectra and C 1s X-ray photoelectron spectra were used for characterization of functional groups linked to carbon shells of nanocomposites. The application of second derivatives of C 1s of X-ray absorption spectra allowed to confirm AA stacking of carbon layers for highly oriented pyrolytic graphite. The low-energy features in C 1s XAS spectra of Ni@C and carbon-shell samples are found to be of a different nature. Most likely, the low-energy C 1s XAS feature of the carbon-shell sample is formed due to hydrogenation of carbon atom. |
ISSN: | 19327447 | DOI: | 10.1021/jp509408w |
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geprüft am 29.04.2024