Crystalline phase in the ultrahigh molecular-weight polyethylene gel solution and xerogel

DC FieldValueLanguage
dc.contributor.authorPakhomov, PM
dc.contributor.authorKhizhnyak, S
dc.contributor.authorReuter, H
dc.contributor.authorTshmel, A
dc.date.accessioned2021-12-23T16:20:13Z-
dc.date.available2021-12-23T16:20:13Z-
dc.date.issued2003
dc.identifier.issn00218995
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/13368-
dc.description.abstractThe transverse and longitudinal sizes of crystallites in thermoreversible polyethylene gels and xerogels were measured using wide-angle X-ray scattering and a low-frequency Raman spectroscopy, and were found to be 10-40 and 4-5 nm, respectively. The experimental data evidence the imperfection of primary crystallites in both dimensions. The gel-to-solid transition results in gaining the direct interaction between crystalline entities with increasing the cracking, on the one hand, and forming the clusters of stacked crystalline platelets linked with regular molecular rods, on the other hand. These contact interaction leads, in addition, to the coiling of a great part of regular sequences that emanate from the crystallite cores to the amorphous region. (C) 2003 Wiley Periodicals, Inc.
dc.language.isoen
dc.publisherJOHN WILEY & SONS INC
dc.relation.ispartofJOURNAL OF APPLIED POLYMER SCIENCE
dc.subjectCHAIN
dc.subjectPolymer Science
dc.titleCrystalline phase in the ultrahigh molecular-weight polyethylene gel solution and xerogel
dc.typejournal article
dc.identifier.doi10.1002/app.12269
dc.identifier.isiISI:000182709700013
dc.description.volume89
dc.description.issue2
dc.description.startpage373
dc.description.endpage378
dc.contributor.researcheridB-8609-2014
dc.publisher.place111 RIVER ST, HOBOKEN, NJ 07030 USA
dcterms.isPartOf.abbreviationJ. Appl. Polym. Sci.
crisitem.author.deptInstitut für Chemie neuer Materialien-
crisitem.author.deptidinstitute11-
crisitem.author.parentorgFB 05 - Biologie/Chemie-
crisitem.author.grandparentorgUniversität Osnabrück-
crisitem.author.netidReHa636-
Show simple item record

Page view(s)

3
Last Week
0
Last month
0
checked on Jun 25, 2024

Google ScholarTM

Check

Altmetric