DC Field | Value | Language |
dc.contributor.author | Yarmoshenko, YM | |
dc.contributor.author | Shamin, SN | |
dc.contributor.author | Elokhina, LV | |
dc.contributor.author | Dolgih, VE | |
dc.contributor.author | Kurmaev, EZ | |
dc.contributor.author | Bartkowski, S | |
dc.contributor.author | Neumann, M | |
dc.contributor.author | Ederer, DL | |
dc.contributor.author | Goransson, K | |
dc.contributor.author | Nolang, B | |
dc.contributor.author | Engstrom, I | |
dc.date.accessioned | 2021-12-23T16:20:31Z | - |
dc.date.available | 2021-12-23T16:20:31Z | - |
dc.date.issued | 1997 | |
dc.identifier.issn | 09538984 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/13487 | - |
dc.description.abstract | A full study of the electronic structure of 4d and 5d silicides (RuSi, RhSi, PdSi, OsSi, IrSi, Ir3Si5, IrSi3, PtSi) is undertaken including XPS VB and XES (Si K beta(1,3) and Si L-2,L-3) measurements and LMTO band structure calculations. It is found that d bands which dominate the density of states are more localized with increasing atomic number Z of the transition metal. A strong hybridization between silicon 3p and transition metal d states occurs over the entire valence band. Si 3s states are found to be not mixed with Si 3p and nd states but Si 3d states participate in bonding and hybridize with transition metal d states. The non-bonding character of the majority of nd states is not confirmed for 4d and 5d silicides. | |
dc.language.iso | en | |
dc.publisher | IOP PUBLISHING LTD | |
dc.relation.ispartof | JOURNAL OF PHYSICS-CONDENSED MATTER | |
dc.subject | CASI2 | |
dc.subject | ELECTRONIC-STRUCTURE | |
dc.subject | MONOSILICIDES | |
dc.subject | NISI2 | |
dc.subject | Physics | |
dc.subject | Physics, Condensed Matter | |
dc.subject | SPECTROSCOPY | |
dc.subject | STATES | |
dc.subject | X-RAY-EMISSION | |
dc.title | Valence band spectra of 4d and 5d silicides | |
dc.type | journal article | |
dc.identifier.doi | 10.1088/0953-8984/9/43/023 | |
dc.identifier.isi | ISI:A1997YD77700023 | |
dc.description.volume | 9 | |
dc.description.issue | 43 | |
dc.description.startpage | 9403 | |
dc.description.endpage | 9414 | |
dc.contributor.orcid | 0000-0001-9716-1318 | |
dc.contributor.orcid | 0000-0003-4625-4930 | |
dc.contributor.orcid | 0000-0001-8213-5926 | |
dc.contributor.orcid | 0000-0001-8971-2052 | |
dc.contributor.researcherid | K-2915-2013 | |
dc.contributor.researcherid | J-4254-2013 | |
dc.contributor.researcherid | K-2922-2013 | |
dc.contributor.researcherid | E-9531-2011 | |
dc.publisher.place | DIRAC HOUSE, TEMPLE BACK, BRISTOL, ENGLAND BS1 6BE | |
dcterms.isPartOf.abbreviation | J. Phys.-Condes. Matter | |