Magnetic and electronic properties of the iron-containing polyoxotungstate [Fe-4(H2O)(10)(beta-SbW9O33)(2)](6-)

DC FieldValueLanguage
dc.contributor.authorPrinz, M.
dc.contributor.authorTakacs, A. F.
dc.contributor.authorSchnack, J.
dc.contributor.authorBalasz, I.
dc.contributor.authorBurzo, E.
dc.contributor.authorKortz, U.
dc.contributor.authorKuepper, K.
dc.contributor.authorNeumann, M.
dc.date.accessioned2021-12-23T16:20:58Z-
dc.date.available2021-12-23T16:20:58Z-
dc.date.issued2006
dc.identifier.issn00218979
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/13673-
dc.description.abstractThe magnetic and x-ray photoelectron spectroscopy (XPS) studies on the transition metal substituted, dimeric polyoxotungstate [Fe-4(H2O)(10)(beta-SbW9O33)(2)](6-) are reported. The magnetic data were analyzed by using an isotropic Heisenberg Hamiltonian. The ground state of the frustrated molecule has a total spin of S=2. The XPS Fe 2p spectra suggest a 2+ formal valence state. The deviation from the contained Fe3+ ions can be explained by charge-transfer effects. (C) 2006 American Institute of Physics.
dc.language.isoen
dc.publisherAMER INST PHYSICS
dc.relation.ispartofJOURNAL OF APPLIED PHYSICS
dc.subjectMOLECULES
dc.subjectPhysics
dc.subjectPhysics, Applied
dc.subjectSPECTROSCOPY
dc.titleMagnetic and electronic properties of the iron-containing polyoxotungstate [Fe-4(H2O)(10)(beta-SbW9O33)(2)](6-)
dc.typejournal article
dc.identifier.doi10.1063/1.2173613
dc.identifier.isiISI:000237404200473
dc.description.volume99
dc.description.issue8
dc.contributor.orcid0000-0003-0702-2723
dc.contributor.researcheridG-1397-2016
dc.contributor.researcheridB-7280-2011
dc.contributor.researcheridA-4079-2008
dc.identifier.eissn10897550
dc.publisher.place1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA
dcterms.isPartOf.abbreviationJ. Appl. Phys.
crisitem.author.deptFB 04 - Physik-
crisitem.author.deptidfb04-
crisitem.author.orcid0000-0003-0702-2723-
crisitem.author.parentorgUniversität Osnabrück-
crisitem.author.netidScJu137-
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