Scanner-Based Capillary Stamping

Autor(en): Hou, Peilong
Kumar, Ravi
Oberleiter, Bastian
Kohns, Richard
Enke, Dirk
Beginn, Uwe 
Fuchs, Harald
Hirtz, Michael
Steinhart, Martin 
Stichwörter: ARRAYS; block copolymers; BLOCK-COPOLYMER NANORODS; Chemistry; Chemistry, Multidisciplinary; Chemistry, Physical; composite materials; DEPOSITION; Materials Science; Materials Science, Multidisciplinary; microcontact printing; MORPHOLOGY; Nanoscience & Nanotechnology; Physics; Physics, Applied; Physics, Condensed Matter; POLYMER PEN LITHOGRAPHY; polymeric materials; porous materials; Science & Technology - Other Topics; TIP
Erscheinungsdatum: 2020
Volumen: 30
Ausgabe: 25
Classical microcontact printing and polymer pen lithography (PPL) involve ink transfer to substrates using solid elastomeric stamps. Ink depletion thus limits the number of successive stamping steps without reinking. Porous stamps developed to overcome this limitation are used only for manual proof-of-principle experiments. Here, porous composite stamps for scanner-based capillary stamping (SCS) that can be mounted on automated printing devices designed for PPL are developed. Porous SCS composite stamps consist of a rigid controlled porous silica glass (CPG) layer and a porous polymeric stamping layer. The latter can be topographically structured with contact elements by replication molding. The mechanical stabilization by the CPG layer ensures that the contact elements are coplanar. SCS allows automated, continuous, high-throughput patterning enabled by ink supply through the porous SCS composite stamps. Even after more than 800 consecutive stamp-substrate contacts without reinking (the porous SCS composite stamps themselves are used as ink reservoirs), ink microdroplets are deposited without deterioration of the pattern quality. However, SCS also allows supply of additional ink during ongoing stamping operations through the pore systems of the porous SCS composite stamps. SCS can easily be adapted for multi-ink patterning and may pave the way for further upscaling of contact lithography.
ISSN: 1616301X
DOI: 10.1002/adfm.202001531

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