Nanostructured Metal/Carbon Hybrids for Electrocatalysis by Direct Carbonization of Inverse Micelle Multilayers
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Jang, Yu Jin | |
dc.contributor.author | Jang, Yoon Hee | |
dc.contributor.author | Han, Sang-Beom | |
dc.contributor.author | Khatua, Dibyendu | |
dc.contributor.author | Hess, Claudia | |
dc.contributor.author | Ahn, Hyungju | |
dc.contributor.author | Ryu, Du Yeol | |
dc.contributor.author | Shin, Kwanwoo | |
dc.contributor.author | Park, Kyung-Won | |
dc.contributor.author | Steinhart, Martin | |
dc.contributor.author | Kim, Dong Ha | |
dc.date.accessioned | 2021-12-23T16:21:40Z | - |
dc.date.available | 2021-12-23T16:21:40Z | - |
dc.date.issued | 2013 | |
dc.identifier.issn | 19360851 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/13973 | - |
dc.description.abstract | A synthetic strategy for the fabrication of graphitic carbon nanomaterials containing highly dispersed arrays of metal nanoparticles is reported. This synthetic strategy involves successive deposition of inverse micelle monolayers containing a metal precursor and reduction of the latter, followed by direct carbonization of the obtained multilayer structure of inverse micelles containing metal nanoparticles. Thus, a ``direct-carbonization'' concept, in which the block copolymer simultaneously serves as soft template and as carbon source, was combined with a multilayer buildup protocol. The inner architecture of the multilayer structures consisting of carbon and metal nanoparticles was studied by X-ray reflectivity, grazing incidence small-angle X-ray scattering, and cross-sectional transmission electron microscopy imaging. The hexagonal near ordering of the metal nanoparticles in the block copolymer micelle multilayers was by and large conserved after carbonization. The resulting carbon structures containing multilayers of highly dispersed metal nanoparticles exhibit superior electrocatalytic activity in formic acid and methanol oxidation, suggesting that they are promising electrode materials for fuel cells. | |
dc.description.sponsorship | National Research Foundation of KoreaNational Research Foundation of Korea; Korean GovernmentKorean Government [2011-0029409, 2012-0009649]; NRF [2011-0022690]; PAL in Korea; This work was supported by National Research Foundation of Korea Grant funded by the Korean Government (2011-0029409; 2012-0009649; Global Ph.D. Fellowship). D. Y. Ryu acknowledges the partial supports by NRF Grant 2011-0022690 and PAL in Korea. The authors are grateful to B. Walkenfort for his support with the TEM investigations as well as Prof. S. Yoon and H.-Y. Shin for the measurement of Raman spectra. | |
dc.language.iso | en | |
dc.publisher | AMER CHEMICAL SOC | |
dc.relation.ispartof | ACS NANO | |
dc.subject | ARRAYS | |
dc.subject | block copolymers | |
dc.subject | BLOCK-COPOLYMERS | |
dc.subject | CATALYSTS | |
dc.subject | Chemistry | |
dc.subject | Chemistry, Multidisciplinary | |
dc.subject | Chemistry, Physical | |
dc.subject | direct carbonization | |
dc.subject | electrodes | |
dc.subject | FUEL-CELLS | |
dc.subject | Materials Science | |
dc.subject | Materials Science, Multidisciplinary | |
dc.subject | MESOPOROUS CARBON | |
dc.subject | metal/carbon hybrids | |
dc.subject | METHANOL | |
dc.subject | NANOFIBERS | |
dc.subject | NANOPARTICLES | |
dc.subject | Nanoscience & Nanotechnology | |
dc.subject | NANOTUBES | |
dc.subject | Science & Technology - Other Topics | |
dc.subject | self-assembly | |
dc.subject | THIN-FILMS | |
dc.title | Nanostructured Metal/Carbon Hybrids for Electrocatalysis by Direct Carbonization of Inverse Micelle Multilayers | |
dc.type | journal article | |
dc.identifier.doi | 10.1021/nn3056115 | |
dc.identifier.isi | ISI:000315618700078 | |
dc.description.volume | 7 | |
dc.description.issue | 2 | |
dc.description.startpage | 1573 | |
dc.description.endpage | 1582 | |
dc.contributor.orcid | 0000-0002-5241-8498 | |
dc.contributor.orcid | 0000-0001-7570-094X | |
dc.contributor.orcid | 0000-0003-0444-0479 | |
dc.contributor.orcid | 0000-0002-7563-8581 | |
dc.contributor.researcherid | E-7868-2017 | |
dc.contributor.researcherid | B-7811-2011 | |
dc.contributor.researcherid | AAA-6531-2020 | |
dc.contributor.researcherid | G-9909-2012 | |
dc.contributor.researcherid | B-3778-2008 | |
dc.contributor.researcherid | AAT-6251-2021 | |
dc.contributor.researcherid | G-8278-2012 | |
dc.identifier.eissn | 1936086X | |
dc.publisher.place | 1155 16TH ST, NW, WASHINGTON, DC 20036 USA | |
dcterms.isPartOf.abbreviation | ACS Nano | |
crisitem.author.orcid | 0000-0002-5241-8498 | - |
crisitem.author.netid | StMa946 | - |
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geprüft am 03.06.2024