Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapods

DC FieldValueLanguage
dc.contributor.authorAvdoshenko, Stanislav M.
dc.contributor.authorFritz, Fabian
dc.contributor.authorSchlesier, Christin
dc.contributor.authorKostanyan, Aram
dc.contributor.authorDreiser, Jan
dc.contributor.authorLuysberg, Martina
dc.contributor.authorPopov, Alexey A.
dc.contributor.authorMeyer, Carola
dc.contributor.authorWesterstrom, Rasmus
dc.date.accessioned2021-12-23T16:22:59Z-
dc.date.available2021-12-23T16:22:59Z-
dc.date.issued2018
dc.identifier.issn20403364
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/14372-
dc.description.abstractThe magnetic ordering and bistability of one-dimensional chains of endofullerene Dy2ScN@C-80 single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMCD), and ab initio calculations. X-ray absorption measurements reveal that the orientation of the encapsulated endofullerenes differs from the isotropic distribution in the bulk sample, indicating a partial ordering of the endofullerenes inside the SWCNTs. The effect of the one-dimensional packing was further investigated by ab initio calculations, demonstrating that for specific tube diameters, the encapsulation is leading to energetically preferential orientations of the endohedral clusters. Additionally, element-specific magnetization curves reveal a decreased magnetic bistability of the encapsulated Dy2ScN@C-80 SMMs compared to the bulk analog.
dc.description.sponsorshipSwedish Research CouncilSwedish Research CouncilEuropean Commission [2015-00455]; Volkswagen Stiftung program ``Integration of Molecular Components in Functional Macroscopic Systems'' [86393, 9200]; DFGGerman Research Foundation (DFG)European Commission [ME 32375/6-1]; ``Niedersachsisches Vorab'' program of the Niedersachsisches Ministerium fur Wissenschaft und Kultur; Marie Sklodowska-Curie actions, EU project SamSD [748635]; European Research Council under the European Unions Horizon 2020 research and innovation programmeEuropean Research Council (ERC) [648295]; Sklodowska Curie Actions [INCA 600398]; This work was financed by the Swedish Research Council (Grant No. 2015-00455), Sklodowska Curie Actions co-founding project INCA 600398, and the Volkswagen Stiftung program ``Integration of Molecular Components in Functional Macroscopic Systems''(Grant No. 86393 and 9200). C. M. acknowledges funding by the DFG project ME 32375/6-1 and the ``Niedersachsisches Vorab'' program of the Niedersachsisches Ministerium fur Wissenschaft und Kultur. S. M. A. acknowledges funding by the Marie Sklodowska-Curie actions, EU project SamSD (grant agreement number 748635). A. A. P. acknowledges the European Research Council under the European Unions Horizon 2020 research and innovation programme (grant no 648295 ``GraM3''). We thank G. Manoharan for Raman measurements on the pristine SWCNTs and Thomas Greber for access to the MPMS3.
dc.language.isoen
dc.publisherROYAL SOC CHEMISTRY
dc.relation.ispartofNANOSCALE
dc.subjectCAGE
dc.subjectChemistry
dc.subjectChemistry, Multidisciplinary
dc.subjectMAGNETORESISTANCE
dc.subjectMaterials Science
dc.subjectMaterials Science, Multidisciplinary
dc.subjectNanoscience & Nanotechnology
dc.subjectPhysics
dc.subjectPhysics, Applied
dc.subjectRAY CIRCULAR-DICHROISM
dc.subjectScience & Technology - Other Topics
dc.subjectSPIN
dc.titlePartial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapods
dc.typejournal article
dc.identifier.doi10.1039/c8nr05386c
dc.identifier.isiISI:000450820400038
dc.description.volume10
dc.description.issue38
dc.description.startpage18153
dc.description.endpage18160
dc.contributor.orcid0000-0001-7480-1271
dc.contributor.orcid0000-0003-4710-4512
dc.contributor.orcid0000-0001-5839-3079
dc.contributor.orcid0000-0002-5613-7570
dc.contributor.orcid0000-0003-0851-2767
dc.contributor.orcid0000-0002-7596-0378
dc.contributor.orcid0000-0002-6304-8795
dc.contributor.researcheridW-6261-2018
dc.contributor.researcheridP-4991-2017
dc.contributor.researcheridG-2578-2010
dc.contributor.researcheridB-6448-2014
dc.contributor.researcheridI-1723-2012
dc.contributor.researcheridA-9937-2011
dc.identifier.eissn20403372
dc.publisher.placeTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
dcterms.isPartOf.abbreviationNanoscale
dcterms.oaStatusGreen Published, Green Accepted, hybrid
crisitem.author.deptUniversität Osnabrück-
crisitem.author.deptUniversität Osnabrück-
crisitem.author.deptUniversität Osnabrück-
crisitem.author.deptUniversität Osnabrück-
crisitem.author.deptUniversität Osnabrück-
crisitem.author.deptUniversität Osnabrück-
crisitem.author.deptFB 04 - Physik-
crisitem.author.deptUniversität Osnabrück-
crisitem.author.deptidfb04-
crisitem.author.orcid0000-0002-6304-8795-
crisitem.author.orcid0000-0001-7480-1271-
crisitem.author.orcid0000-0002-5613-7570-
crisitem.author.orcid0000-0003-0851-2767-
crisitem.author.orcid0000-0003-4710-4512-
crisitem.author.parentorgUniversität Osnabrück-
crisitem.author.netidAvSt001-
crisitem.author.netidFrFa001-
crisitem.author.netidScCh001-
crisitem.author.netidKoAr001-
crisitem.author.netidDrJa001-
crisitem.author.netidLuMa001-
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crisitem.author.netidMeCa197-
crisitem.author.netidWeRa001-
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