Nanoscale x-ray investigation of magnetic metallofullerene peapods
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Fritz, Fabian | |
dc.contributor.author | Westerstrom, Rasmus | |
dc.contributor.author | Kostanyan, Aram | |
dc.contributor.author | Schlesier, Christin | |
dc.contributor.author | Dreiser, Jan | |
dc.contributor.author | Watts, Benjamin | |
dc.contributor.author | Houben, Lothar | |
dc.contributor.author | Luysberg, Martina | |
dc.contributor.author | Avdoshenko, Stanislav M. | |
dc.contributor.author | Popov, Alexey A. | |
dc.contributor.author | Schneider, Claus M. | |
dc.contributor.author | Meyer, Carola | |
dc.date.accessioned | 2021-12-23T16:23:03Z | - |
dc.date.available | 2021-12-23T16:23:03Z | - |
dc.date.issued | 2017 | |
dc.identifier.issn | 09574484 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/14398 | - |
dc.description.abstract | Endohedral lanthanide ions packed inside carbon nanotubes (CNTs) in a one-dimensional assembly have been studied with a combination of high resolution transmission electron microscopy (HRTEM), scanning transmission x-ray microscopy (STXM), and x-ray magnetic circular dichroism (XMCD). By correlating HRTEM and STXM images we show that structures down to 30 nm are resolved with chemical contrast and record x-ray absorption spectra from endohedral lanthanide ions embedded in individual nanoscale CNT bundles. XMCD measurements of an Er3N@C-80 bulk sample and a macroscopic assembly of filled CNTs indicate that the magnetic properties of the endohedral Er3+ ions are unchanged when encapsulated in CNTs. This study demonstrates the feasibility of local magnetic x-ray characterisation of low concentrations of lanthanide ions embedded in molecular nanostructures. | |
dc.description.sponsorship | Bundesministerium fur Bildung und Forschung (BMBF)Federal Ministry of Education & Research (BMBF) [05KS4WE1/6, 05KS7WE1]; Volkswagen Stiftung program `Integration of Molecular Components in Functional Macroscopic Systems' [86393, 9200]; DFG SPP1601, the Swedish Research Council [201500455]; Swedish Research CouncilSwedish Research CouncilEuropean Commission [201500455]; Sklodowska Curie Actions co-founding project INCA [600398]; European Research Council (ERC) under the European Union's HorizonEuropean Research Council (ERC) [648295 `GraM3']; We thank the staff at the SLS for help: X-Treme beamline: C. Piamonteze, PolLux beamline: B. Sarafimov for technical support; The PolLux end station was financed by the Bundesministerium fur Bildung und Forschung (BMBF) through contracts 05KS4WE1/6 and 05KS7WE1. We thank AN. Khlobystov (Nottingham University) and T. Chamberlain (University of Leeds) for fruitful discussions about the CO2 filling and for information regarding the setup of the equipment. This work was financed by the Volkswagen Stiftung program `Integration of Molecular Components in Functional Macroscopic Systems' (Grant Nos. 86393 and 9200), the DFG SPP1601, the Swedish Research Council (Grant No. 201500455) and Sklodowska Curie Actions co-founding project INCA 600398. CM acknowledges funding by the `Niedersachsisches Vorab' program of the Niedersachsisches Ministerium'fur Wissenschaft und Kultur. AAP acknowledges funding by the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation program (grant agreement No 648295 `GraM3'). Computational resources were provided by the Center for Information Services and High Performance Computing (ZIH) in TU Dresden. | |
dc.language.iso | en | |
dc.publisher | IOP PUBLISHING LTD | |
dc.relation.ispartof | NANOTECHNOLOGY | |
dc.subject | CARBON NANOTUBES | |
dc.subject | CIRCULAR-DICHROISM | |
dc.subject | CNT | |
dc.subject | endohedral fullerenes | |
dc.subject | FIELD | |
dc.subject | FULLERENES | |
dc.subject | HRTEM | |
dc.subject | Materials Science | |
dc.subject | Materials Science, Multidisciplinary | |
dc.subject | Nanoscience & Nanotechnology | |
dc.subject | Physics | |
dc.subject | Physics, Applied | |
dc.subject | Science & Technology - Other Topics | |
dc.subject | SPECTROSCOPY | |
dc.subject | STXM | |
dc.subject | XMCD | |
dc.title | Nanoscale x-ray investigation of magnetic metallofullerene peapods | |
dc.type | journal article | |
dc.identifier.doi | 10.1088/1361-6528/aa8b4c | |
dc.identifier.isi | ISI:000412204000001 | |
dc.description.volume | 28 | |
dc.description.issue | 43 | |
dc.contributor.orcid | 0000-0002-7596-0378 | |
dc.contributor.orcid | 0000-0001-7480-1271 | |
dc.contributor.orcid | 0000-0003-0851-2767 | |
dc.contributor.orcid | 0000-0002-3920-6255 | |
dc.contributor.orcid | 0000-0002-5613-7570 | |
dc.contributor.orcid | 0000-0003-4710-4512 | |
dc.contributor.orcid | 0000-0001-5839-3079 | |
dc.contributor.orcid | 0000-0003-0200-3611 | |
dc.contributor.orcid | 0000-0002-6304-8795 | |
dc.contributor.orcid | 0000-0003-2330-2338 | |
dc.contributor.researcherid | A-9937-2011 | |
dc.contributor.researcherid | W-6261-2018 | |
dc.contributor.researcherid | I-1723-2012 | |
dc.contributor.researcherid | H-7453-2012 | |
dc.contributor.researcherid | B-6448-2014 | |
dc.contributor.researcherid | P-4991-2017 | |
dc.contributor.researcherid | G-2578-2010 | |
dc.contributor.researcherid | K-3593-2013 | |
dc.identifier.eissn | 13616528 | |
dc.publisher.place | TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND | |
dcterms.isPartOf.abbreviation | Nanotechnology | |
dcterms.oaStatus | Green Submitted | |
crisitem.author.dept | Universität Osnabrück | - |
crisitem.author.dept | Universität Osnabrück | - |
crisitem.author.dept | Universität Osnabrück | - |
crisitem.author.dept | Universität Osnabrück | - |
crisitem.author.dept | Universität Osnabrück | - |
crisitem.author.dept | Universität Osnabrück | - |
crisitem.author.dept | Universität Osnabrück | - |
crisitem.author.dept | Universität Osnabrück | - |
crisitem.author.dept | Universität Osnabrück | - |
crisitem.author.dept | FB 04 - Physik | - |
crisitem.author.deptid | fb04 | - |
crisitem.author.orcid | 0000-0002-6304-8795 | - |
crisitem.author.orcid | 0000-0003-4710-4512 | - |
crisitem.author.orcid | 0000-0001-7480-1271 | - |
crisitem.author.orcid | 0000-0003-2330-2338 | - |
crisitem.author.orcid | 0000-0003-0200-3611 | - |
crisitem.author.orcid | 0000-0002-5613-7570 | - |
crisitem.author.orcid | 0000-0003-0851-2767 | - |
crisitem.author.parentorg | Universität Osnabrück | - |
crisitem.author.netid | FrFa001 | - |
crisitem.author.netid | WeRa001 | - |
crisitem.author.netid | KoAr001 | - |
crisitem.author.netid | ScCh001 | - |
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crisitem.author.netid | MeCa197 | - |
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geprüft am 19.05.2024