Mixed-Valent Mn-16-Containing Heteropolyanions: Tuning of Oxidation State and Associated Physicochemical Properties
DC Element | Wert | Sprache |
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dc.contributor.author | Haider, Ali | |
dc.contributor.author | Ibrahim, Masooma | |
dc.contributor.author | Bassil, Bassem S. | |
dc.contributor.author | Carey, Akina M. | |
dc.contributor.author | Anh Nguyen Viet | |
dc.contributor.author | Xing, Xiaolin | |
dc.contributor.author | Ayass, Wassim W. | |
dc.contributor.author | Minambres, Juan F. | |
dc.contributor.author | Liu, Rongji | |
dc.contributor.author | Zhang, Guangjin | |
dc.contributor.author | Keita, Bineta | |
dc.contributor.author | Mereacre, Valeriu | |
dc.contributor.author | Powell, Annie K. | |
dc.contributor.author | Balinski, Kamil | |
dc.contributor.author | N'Diaye, Alpha T. | |
dc.contributor.author | Kuepper, Karsten | |
dc.contributor.author | Chen, Han-Yi | |
dc.contributor.author | Stimming, Ulrich | |
dc.contributor.author | Kortz, Ulrich | |
dc.date.accessioned | 2021-12-23T16:24:03Z | - |
dc.date.available | 2021-12-23T16:24:03Z | - |
dc.date.issued | 2016 | |
dc.identifier.issn | 00201669 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/14760 | - |
dc.description.abstract | The two 16-manganese-containing, Keggin-based 36-tungsto-4-silicates [(Mn10Mn6O6)-Mn-III-O-II(OH)(6)(PO4)(4)(A-alpha-SiW9O34)(4)](28-) (1) and [(Mn4Mn12II)-Mn-III(OH)(12)(PO4)(4)(A-alpha-SiW9O34)(4)](28-) (2) have been prepared by reaction of the trilacunary Keggin precursor [A-alpha-SiW9O34](10-) with either Mn(OOCCH3)(3)center dot 2H(2)O (for 1) or MnCl2 center dot 4H2O (for 2), in aqueous phosphate solution at pH 9. Polyanions 1 and 2 comprise mixed-valent, cationic {(MnMnI6O6)-Mn-III-I-II(OH)(6)}(24+) and {(Mn10Mn6O6)-Mn-III-O-II(OH)(6)(PO4)(4)} cores, respectively, encapsulated by four phosphate groups and four {SiW9} units in a tetrahedral fashion. Both polyanions were structurally and compositionally Characterized by single-crystal XRD, IR, therrnogravimetric analysis, and X-ray absorption,, spectroscopy. Furthermore, studies were performed probing, the magnetic, electrochemical, oxidation catalytic, and Li-ion battery performance of 1 and 2. | |
dc.description.sponsorship | German Science Foundation (DFG)German Research Foundation (DFG) [KO 2288/20-1]; CMST COST Action [CM1203]; Jacobs University; Chinese Academy of Sciences President's International Fellowship Initiative [2015VMA041]; DAADDeutscher Akademischer Austausch Dienst (DAAD)European Commission; DFGGerman Research Foundation (DFG)European Commission; Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT); Higher Education Commission of PakistanHigher Education Commission of Pakistan; Office of Science, Office of Basic Energy Sciences, of the U.S. Department of EnergyUnited States Department of Energy (DOE) [DE-AC02-05CH11231]; National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21371173]; TUM CREATE; National Research Foundation of SingaporeNational Research Foundation, Singapore; Newcastle University; U.K. thanks the German Science Foundation (DFG, KO 2288/20-1), the CMST COST Action CM1203 (PoCheMoN), and Jacobs University for research support, and kindly acknowledges the Chinese Academy of Sciences President's International Fellowship Initiative (Grant No. 2015VMA041). A.H. thanks DAAD for a doctoral fellowship. M.I. thanks DFG and Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), for a postdoctoral fellowship, and she also thanks DAAD and the Higher Education Commission of Pakistan for a doctoral fellowship (Jacobs University). She also acknowledges the University of Balochistan, Quetta, Pakistan, for allowing her to pursue Ph.D. (Jacobs University) and postdoctoral (KIT) studies in Germany. The Advanced Light Source is supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy, under Contract No. DE-AC02-05CH11231. G.Z. thanks the National Science Foundation of China (No. 21371173) for the funding and research support. H.-Y.C. and U.S. thank TUM CREATE, National Research Foundation of Singapore, and Newcastle University for research and funding support. Figures 1 and 2 were generated by Diamond, Version 3.2 (copyright Crystal Impact GbR). | |
dc.language.iso | en | |
dc.publisher | AMER CHEMICAL SOC | |
dc.relation.ispartof | INORGANIC CHEMISTRY | |
dc.subject | BUILDING-BLOCKS | |
dc.subject | Chemistry | |
dc.subject | Chemistry, Inorganic & Nuclear | |
dc.subject | CRYSTAL-STRUCTURE | |
dc.subject | DIMERIC POLYOXOANIONS | |
dc.subject | ELECTROCHEMICAL GENERATION | |
dc.subject | FREE AEROBIC OXIDATION | |
dc.subject | MN-III | |
dc.subject | POLYOXOMETALATE | |
dc.subject | SINGLE-MOLECULE MAGNET | |
dc.subject | TRANSITION-METAL | |
dc.subject | WATER OXIDATION | |
dc.title | Mixed-Valent Mn-16-Containing Heteropolyanions: Tuning of Oxidation State and Associated Physicochemical Properties | |
dc.type | journal article | |
dc.identifier.doi | 10.1021/acs.inorgchem.5b02503 | |
dc.identifier.isi | ISI:000372677800013 | |
dc.description.volume | 55 | |
dc.description.issue | 6 | |
dc.description.startpage | 2755 | |
dc.description.endpage | 2764 | |
dc.contributor.orcid | 0000-0003-3944-7427 | |
dc.contributor.orcid | 0000-0002-8520-8585 | |
dc.contributor.orcid | 0000-0001-8755-2454 | |
dc.contributor.orcid | 0000-0001-9429-9776 | |
dc.contributor.orcid | 0000-0002-4978-1245 | |
dc.contributor.orcid | 0000-0002-4270-3404 | |
dc.contributor.researcherid | B-8665-2012 | |
dc.contributor.researcherid | G-1397-2016 | |
dc.contributor.researcherid | P-1913-2016 | |
dc.contributor.researcherid | AAD-7616-2021 | |
dc.contributor.researcherid | D-1110-2018 | |
dc.contributor.researcherid | AAA-3101-2020 | |
dc.contributor.researcherid | AAM-7849-2020 | |
dc.identifier.eissn | 1520510X | |
dc.publisher.place | 1155 16TH ST, NW, WASHINGTON, DC 20036 USA | |
dcterms.isPartOf.abbreviation | Inorg. Chem. | |
dcterms.oaStatus | Green Submitted | |
crisitem.author.dept | FB 04 - Physik | - |
crisitem.author.deptid | fb04 | - |
crisitem.author.parentorg | Universität Osnabrück | - |
crisitem.author.netid | KuKa120 | - |
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