[Ga(en)3][Ga3Se7(en)] • H2O: A gallium chalcogenide with chains of [Ga3Se6Se2/2(en)]3- bicycles [Ga(en)3][Ga3Se7(en)] • H2O: Ein galliumchalkogenid mit ketten aus [Ga3Se6Se2/2(en)]3-·bicyclen
DC Element | Wert | Sprache |
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dc.contributor.author | Fehlker, A. | |
dc.contributor.author | Blachnik, R. | |
dc.contributor.author | Reuter, H. | |
dc.date.accessioned | 2021-12-23T16:27:11Z | - |
dc.date.available | 2021-12-23T16:27:11Z | - |
dc.date.issued | 1999 | |
dc.identifier.issn | 00442313 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/15318 | - |
dc.description.abstract | The new selenidogallate [Ga(en)3][Ga3Se7(en)] · H2O (I) was produced from a ethylendiamine suspension of Ga and Se at 130°C. I crystallizes in the orthorhombic space group Pna21 with unit constants a=1347.9(3) pm, b=961.6(1) pm, c=1967.6(4) pm and Z=4. The crystal structure contains an anion so far not observed in gallium chalcogenides. It is built from [Ga3Se6Se2/2(en)]3- bicycles of three GaIIIL4 tetrahedra (L=en, Se) connected via selenium corners to linear chains. The cations, GaIII ions coordinated by three ethylendiamine in a distorted octahedral geometry are positioned in the holes of the hexagonal rod packing of these chains. | |
dc.language.iso | de | |
dc.publisher | Wiley-VCH Verlag | |
dc.relation.ispartof | Zeitschrift fur Anorganische und Allgemeine Chemie | |
dc.subject | Gallium | |
dc.subject | Hydrothermal Synthesis | |
dc.subject | Polyanions | |
dc.subject | Selenidogallate(III) | |
dc.subject | Structure | |
dc.title | [Ga(en)3][Ga3Se7(en)] • H2O: A gallium chalcogenide with chains of [Ga3Se6Se2/2(en)]3- bicycles [Ga(en)3][Ga3Se7(en)] • H2O: Ein galliumchalkogenid mit ketten aus [Ga3Se6Se2/2(en)]3-·bicyclen | |
dc.type | journal article | |
dc.identifier.doi | 10.1002/(sici)1521-3749(199907)625:7<1225::aid-zaac1225>3.0.co;2-h | |
dc.identifier.scopus | 2-s2.0-0041020406 | |
dc.identifier.url | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0041020406&doi=10.1002%2f%28sici%291521-3749%28199907%29625%3a7%3c1225%3a%3aaid-zaac1225%3e3.0.co%3b2-h&partnerID=40&md5=8d0018ce828c858d209ac2bbb6478bc9 | |
dc.description.volume | 625 | |
dc.description.issue | 7 | |
dc.description.startpage | 1225 | |
dc.description.endpage | 1228 | |
dcterms.isPartOf.abbreviation | Z. Anorg. Allg. Chem. | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | ReHa636 | - |
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