Classical and quantum magnetism in giant Keplerate magnetic molecules
| Autor(en): | Müller, A. Luban, M. Schröder, C. Modler, R. Kögerler, P. Axenovich, M. Schnack, J. Canfield, P. Bud'ko, S. Harrison, N. |
Stichwörter: | Cage compounds; Cluster compounds; Magnetic molecules; Magnetic properties; Molecules; Paramagnetic molecules; Polyoxometalates; Quantitative agreement; Quantum magnetism; Synthesis (chemical); Theoretical modeling, Magnetism; Topology; Topology, Cage compounds | Erscheinungsdatum: | 2001 | Herausgeber: | Wiley-VCH Verlag | Journal: | ChemPhysChem | Volumen: | 2 | Ausgabe: | 8-9 | Startseite: | 517 | Seitenende: | 521 | Zusammenfassung: | Complementary theoretical modeling methods are presented for the classical and quantum Heisenberg model to explain the magnetic properties of nanometer-sized magnetic molecules. Excellent quantitative agreement is achieved between our experimental data down to 0.1 K and for fields up to 60 Tesla and our theoretical results for the giant Keplerate species {Mo72Fe30}, by far the largest paramagnetic molecule synthesized to date. © Wiley-VCH-Verlag GmbH, 2001. |
ISSN: | 14394235 | DOI: | 10.1002/1439-7641(20010917)2:8/9<517::aid-cphc517>3.3.co;2-t | Externe URL: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85085674366&doi=10.1002%2f1439-7641%2820010917%292%3a8%2f9%3c517%3a%3aaid-cphc517%3e3.3.co%3b2-t&partnerID=40&md5=f4dc8baad6d19704bad1d1e997948136 |
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