Dilithium hexahydroxidostannate(IV) dihydrate, a second monoclinic modification with a layer structure
DC Element | Wert | Sprache |
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dc.contributor.author | Kamaha, S. | |
dc.contributor.author | Reuter, H. | |
dc.date.accessioned | 2021-12-23T16:30:32Z | - |
dc.date.available | 2021-12-23T16:30:32Z | - |
dc.date.issued | 2013 | |
dc.identifier.issn | 16005368 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/16627 | - |
dc.description.abstract | The title compound, Li2[Sn(OH)6]·2H 2O, is dimorphic. As for the previously described α-modification, the title β-modification crystallizes in the monoclinic system and contains the same primary building units, viz [Sn(OH) 6]2- octahedra and [Li(μ2-OH)3(H 2O)] tetrahedra. In contrast to the Sn - O bond lengths that are very similar in both modifications, the Li - O bond lengths differ significantly, in particular those involving the water molecule. In the new β-modification, the primary building units are linked into layers parallel to (010). The [Sn(OH)6]2- octahedra (-1 symmetry) form hexagonal nets and the [Li(μ2-OH)3(H2O)] tetrahedra are situated in between, with their apices in an alternating fashion up and down. O - H⋯O hydrogen bonds between OH groups and water molecules exist within the layers as well as between them. | |
dc.language.iso | en | |
dc.relation.ispartof | Acta Crystallographica Section E: Structure Reports Online | |
dc.title | Dilithium hexahydroxidostannate(IV) dihydrate, a second monoclinic modification with a layer structure | |
dc.type | journal article | |
dc.identifier.doi | 10.1107/S1600536813008416 | |
dc.identifier.scopus | 2-s2.0-84877287692 | |
dc.identifier.url | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84877287692&doi=10.1107%2fS1600536813008416&partnerID=40&md5=c477328df0ede3767eb04dbfeb8f3e15 | |
dc.description.volume | 69 | |
dc.description.issue | 5 | |
dc.description.startpage | i25 | |
dcterms.isPartOf.abbreviation | Acta Crystallogr. Sect. E Struct. Rep. Online | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | ReHa636 | - |
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geprüft am 07.06.2024