DC Field | Value | Language |
dc.contributor.author | Seela, F | |
dc.contributor.author | Heckel, M | |
dc.contributor.author | Rosemeyer, H | |
dc.date.accessioned | 2021-12-23T15:57:02Z | - |
dc.date.available | 2021-12-23T15:57:02Z | - |
dc.date.issued | 1996 | |
dc.identifier.issn | 0018019X | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/2669 | - |
dc.description.abstract | Oligonucleotides containing (2'-deoxy-beta-D-xylofuranosyl)guanine have been prepared. For this purpose 2-aminoadenosine (5) was synthesized and converted to 2'-deoxy-beta-D-xyloguanosine (1). The related 2'-deoxy-beta-D-xyloisoguanosine (3) and 2'-deoxy-beta-D-xyloxanthosine (4) were also synthesized. Compound 1 was converted to the phosphonate and phosphoramidite building blocks 10 and 11, respectively. The oligodeoxynucleotide (5'-3')d(xG-xT-xA-xG-xA-xA-xT-xT-xC-xT-xA-xC-T) (18) formed a duplex with the same T-m as the parent (5'-3')-(G-T-A-G-A-A-T-T-C-T-A-C) (19), but with an inverted CD spectrum. | |
dc.language.iso | en | |
dc.publisher | NEW SWISS CHEMICAL SOC | |
dc.relation.ispartof | HELVETICA CHIMICA ACTA | |
dc.subject | ACID RELATED-COMPOUNDS | |
dc.subject | BACKBONE | |
dc.subject | BUILDING-BLOCKS | |
dc.subject | Chemistry | |
dc.subject | Chemistry, Multidisciplinary | |
dc.subject | NUCLEOSIDES | |
dc.subject | SOLID-PHASE SYNTHESIS | |
dc.subject | STABILITY | |
dc.title | Xylose-DNA containing the four natural bases | |
dc.type | journal article | |
dc.identifier.doi | 10.1002/hlca.19960790518 | |
dc.identifier.isi | ISI:A1996VC76000017 | |
dc.description.volume | 79 | |
dc.description.issue | 5 | |
dc.description.startpage | 1451 | |
dc.description.endpage | 1461 | |
dc.publisher.place | VERLAG HELVETICA CHIMICA ACTA, MALZGASSE 21, POSTFACH 313, CH-4010 BASEL, SWITZERLAND | |
dcterms.isPartOf.abbreviation | Helv. Chim. Acta | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | RoHe783 | - |