Monoorganotin-polyoxometal-compounds. III. Synthesis and crystal structure of [((BuSn)-Bu-n)(9)((VO)-O-V)(3)O-14(OH)(6)Cl-2(dmso)(2)]center dot 3DMSO
DC Element | Wert | Sprache |
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dc.contributor.author | Izaaryene, M | |
dc.contributor.author | Kastner, G | |
dc.contributor.author | Reuter, H | |
dc.date.accessioned | 2021-12-23T15:57:43Z | - |
dc.date.available | 2021-12-23T15:57:43Z | - |
dc.date.issued | 2005 | |
dc.identifier.issn | 00442968 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/3087 | - |
dc.description.abstract | The synthesis, molecular and crystal structure of ((BuSn)-Bu-n)(9)((VO)-O-V)(3)O-14(OH)(6)Cl-2(dmso)(2). 3 DMSO (1) are described. The yellow compound crystallizes in the monoclinic space group P2(1)/n (No. 14) with a = 17.961(5) angstrom, b 19.222(4) angstrom, c = 26.748(6) angstrom, beta = 106.776(2)degrees, V = 8842(4) angstrom(3), Z = 4. The neutral monoorganotin-polyoxovanadium molecule ((BuSn)-Bu-n)(9)((VO)-O-V)(3)O-14(OH)(6)Cl-2 x (dmso)(2) (1a) shows the same distorted icosahedral arrangement of the metal atoms and a very similar metal-oxygen framework as the well known [((PrSn)-Pr-1)(12)O-14(OH)(6)](2+) ion (2) from which it can be derived formally by substitution of three square pyramidally coordinated {RSnO4} groups by three {OVO4} groups of the same geometry. In addition, two further {RSnO4} groups are replaced by two octahedral {RSnO3Cl(dmso)} units. | |
dc.language.iso | en | |
dc.publisher | WALTER DE GRUYTER GMBH | |
dc.relation.ispartof | ZEITSCHRIFT FUR KRISTALLOGRAPHIE | |
dc.subject | Crystallography | |
dc.subject | heteropolyoxometal compounds | |
dc.subject | HYDROLYSIS | |
dc.subject | organotin compounds | |
dc.subject | single crystal structure analysis | |
dc.subject | TIN | |
dc.subject | vanadium | |
dc.subject | X-ray diffraction | |
dc.title | Monoorganotin-polyoxometal-compounds. III. Synthesis and crystal structure of [((BuSn)-Bu-n)(9)((VO)-O-V)(3)O-14(OH)(6)Cl-2(dmso)(2)]center dot 3DMSO | |
dc.type | journal article | |
dc.identifier.doi | 10.1524/zkri.220.7.622.67107 | |
dc.identifier.isi | ISI:000230672300006 | |
dc.description.volume | 220 | |
dc.description.issue | 7 | |
dc.description.startpage | 622 | |
dc.description.endpage | 625 | |
dc.contributor.researcherid | H-9847-2014 | |
dc.publisher.place | GENTHINER STRASSE 13, D-10785 BERLIN, GERMANY | |
dcterms.isPartOf.abbreviation | Z. Kristall. | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | ReHa636 | - |
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