DC Field | Value | Language |
dc.contributor.author | Reuter, H | |
dc.contributor.author | Bargon, G | |
dc.date.accessioned | 2021-12-23T15:57:45Z | - |
dc.date.available | 2021-12-23T15:57:45Z | - |
dc.date.issued | 1997 | |
dc.identifier.issn | 00442313 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/3112 | - |
dc.description.abstract | Colourless crystals of Li-2[Sn(OH)(6)]. 2H(2)O were synthesized by reaction of SnCl4 with LiOH in aqueous solution. The crystal structure was determined from single crystal data. Li-2[Sn(OH)(6)]. 2H(2)O: monoclinic, P2(1)/n (Nr.14), a=502.3(1), b=692.3(1), c=1020.2(3)pm, beta=99.78(1)degrees, V=349.6(2).10(6) pm(3), Z = 2, R/Rw = 0.0192/0.0472, N(I) > 2 sigma(I) = 1527, N(Par.)= 54. Within the crystal structure only slightly distorted octahedrally [Sn(OH)(6)](2-) ions are bonded via hydrogen bonds with water molecules forming layers, which themselve are linked by tetrahedrally coordinated Li ions; the structure is in accordance with the IR-data and the results of the Sn-119 solid state NMR-spectroscopy; the hydrat water is eliminated at 117.1 degrees C, the condensation reaction - forming the ternary oxide - takes place at 257.7 degrees C. | |
dc.language.iso | de | |
dc.publisher | WILEY-V C H VERLAG GMBH | |
dc.relation.ispartof | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | |
dc.subject | Chemistry | |
dc.subject | Chemistry, Inorganic & Nuclear | |
dc.subject | crystal structure | |
dc.subject | IR-data | |
dc.subject | lithium hexahydroxostannate(IV) dihydrate | |
dc.subject | single crystal growth | |
dc.subject | thermal decomposition | |
dc.title | Ternary hydroxides. I - Synthesis, structure, and properties of Li-2[Sn(OH)(6)]center dot 2H(2)O | |
dc.type | journal article | |
dc.identifier.doi | 10.1002/zaac.19976231224 | |
dc.identifier.isi | ISI:000071489300023 | |
dc.description.volume | 623 | |
dc.description.issue | 12 | |
dc.description.startpage | 1978 | |
dc.description.endpage | 1982 | |
dc.contributor.orcid | 0000-0003-0394-7999 | |
dc.contributor.researcherid | H-9847-2014 | |
dc.contributor.researcherid | B-8544-2008 | |
dc.publisher.place | MUHLENSTRASSE 33-34, D-13187 BERLIN, GERMANY | |
dcterms.isPartOf.abbreviation | Z. Anorg. Allg. Chem. | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | ReHa636 | - |