Crystal structure of a one-dimensional coordination polymer of tin(IV) bromide with 1,4-dithiane
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Reuter, Hans | |
dc.contributor.author | Roewekamp-Krugley, Natalia | |
dc.contributor.author | Imwalle, Marius | |
dc.contributor.author | Keil, Simona | |
dc.contributor.author | Reichelt, Martin | |
dc.date.accessioned | 2021-12-23T15:58:21Z | - |
dc.date.available | 2021-12-23T15:58:21Z | - |
dc.date.issued | 2015 | |
dc.identifier.issn | 20569890 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/3341 | - |
dc.description.abstract | {The title compound, [SnBr4(C4H8S2)] {systematic name: catenapoly[[}tetrabromidotin(IV)]-mu-1,4-dithiane-kappa S-2:S']}, represents the first 1,4-dithiane complex with tin as coordination centre. The asymmetric unit consist of half a formula unit with the tin(IV) atom at the centre of symmetry at 0,0,1/2 (Wyckoff symbol b) and a centrosymmetric 1,4-dithiane molecule with the centre of symmetry in 1/2,0,1 (Wyckoff symbol c). The tin(IV) atom is coordinated in a distorted octahedral manner by the four bromine atoms and two sulfur atoms of two 1,4-dithiane molecules in a trans-position. Sn Bro [mean value: 2.561 (5) angstrom] and Sn-S distances [2.6546 (6) angstrom] are in the typical range for octahedrally coordinated tin(IV) atoms and the dithiane molecule adopts a chair conformation. The one-dimensional polymeric chains propagate along the [101] direction with weak intermolecular Br center dot center dot center dot Br [3.5724 (4) angstrom] between parallel chains and weak Br center dot center dot center dot H interactions [2.944-2.993 angstrom] within the chains.} | |
dc.description.sponsorship | Deutsche ForschungsgemeinschaftGerman Research Foundation (DFG); We thanks the state of Lower-Saxony and the Deutsche Forschungsgemeinschaft for funding the diffractometer. | |
dc.language.iso | en | |
dc.publisher | INT UNION CRYSTALLOGRAPHY | |
dc.relation.ispartof | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | |
dc.subject | 1,4-dithiane | |
dc.subject | Br center dot center dot center dot Br interactions | |
dc.subject | Br center dot center dot center dot H interactions | |
dc.subject | COMPLEXES | |
dc.subject | coordination polymer | |
dc.subject | crystal structure | |
dc.subject | Crystallography | |
dc.subject | tin(IV) bromide | |
dc.title | Crystal structure of a one-dimensional coordination polymer of tin(IV) bromide with 1,4-dithiane | |
dc.type | journal article | |
dc.identifier.doi | 10.1107/S2056989015023932 | |
dc.identifier.isi | ISI:000370762300032 | |
dc.description.volume | 71 | |
dc.description.issue | 12 | |
dc.description.startpage | M267-U422 | |
dc.publisher.place | 2 ABBEY SQ, CHESTER, CH1 2HU, ENGLAND | |
dcterms.isPartOf.abbreviation | Acta Crystallogr. Sect. E.-Crystallogr. Commun. | |
dcterms.oaStatus | Green Published, gold | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | ReHa636 | - |
Seitenaufrufe
2
Letzte Woche
0
0
Letzter Monat
0
0
geprüft am 10.06.2024