Dimer/tetramer motifs determine amphiphilic hydrazine fibril structures on graphite
DC Element | Wert | Sprache |
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dc.contributor.author | Thomas, Loji K. | |
dc.contributor.author | Diek, Nadine | |
dc.contributor.author | Beginn, Uwe | |
dc.contributor.author | Reichling, Michael | |
dc.date.accessioned | 2021-12-23T15:58:41Z | - |
dc.date.available | 2021-12-23T15:58:41Z | - |
dc.date.issued | 2012 | |
dc.identifier.issn | 21904286 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/3511 | - |
dc.description.abstract | Fibril structures are produced at a solvent-graphite interface by self-assembly of custom-designed symmetric and asymmetric amphiphilic benzamide derivatives bearing C-10 aliphatic chains. Scanning tunnelling microscopy (STM) studies reveal geometry-dependent internal structures for the elementary fibrils of the two molecules that are distinctly different from known mesophase bulk structures. The structures are described by building-block models based on hydrogen-bonded dimer and tetramer precursors of hydrazines. The closure and growth in length of building units into fibrils takes place through van der Waals forces acting between the dangling alkyl chains. The nanoscale morphology is a consequence of the basic molecular geometry, where it follows that a closure to form a fibril is not always likely for the doubly substituted hydrazine. Therefore, we also observe crystallite formation. | |
dc.description.sponsorship | PhD program ``Synthesis and Characterization of surfaces and Interfaces assembled from Clusters and Molecules''; State of Niedersachsen, Germany; This work has been supported by the PhD program ``Synthesis and Characterization of surfaces and Interfaces assembled from Clusters and Molecules'' funded by the State of Niedersachsen, Germany. | |
dc.language.iso | en | |
dc.publisher | BEILSTEIN-INSTITUT | |
dc.relation.ispartof | BEILSTEIN JOURNAL OF NANOTECHNOLOGY | |
dc.subject | ACID | |
dc.subject | CHAINS | |
dc.subject | CHARGE-TRANSPORT | |
dc.subject | DISCOTIC LIQUID-CRYSTALS | |
dc.subject | DYNAMICS | |
dc.subject | fibrils | |
dc.subject | graphite | |
dc.subject | hydrazide | |
dc.subject | hydrazine | |
dc.subject | INTERFACE | |
dc.subject | Materials Science | |
dc.subject | Materials Science, Multidisciplinary | |
dc.subject | Nanoscience & Nanotechnology | |
dc.subject | NANOSTRUCTURES | |
dc.subject | NANOWIRES | |
dc.subject | Physics | |
dc.subject | Physics, Applied | |
dc.subject | SCANNING-TUNNELING-MICROSCOPY | |
dc.subject | Science & Technology - Other Topics | |
dc.subject | self-assembly | |
dc.subject | STM | |
dc.subject | SURFACE | |
dc.title | Dimer/tetramer motifs determine amphiphilic hydrazine fibril structures on graphite | |
dc.type | journal article | |
dc.identifier.doi | 10.3762/bjnano.3.75 | |
dc.identifier.isi | ISI:000308978100001 | |
dc.description.volume | 3 | |
dc.description.startpage | 658 | |
dc.description.endpage | 666 | |
dc.contributor.orcid | 0000-0003-3186-9000 | |
dc.contributor.researcherid | B-1123-2011 | |
dc.publisher.place | TRAKEHNER STRASSE 7-9, FRANKFURT AM MAIN, 60487, GERMANY | |
dcterms.isPartOf.abbreviation | Beilstein J. Nanotechnol. | |
dcterms.oaStatus | Green Published, Green Submitted, gold | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.dept | FB 04 - Physik | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.deptid | fb04 | - |
crisitem.author.orcid | 0000-0003-3186-9000 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.parentorg | Universität Osnabrück | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | DiNa633 | - |
crisitem.author.netid | BeUw846 | - |
crisitem.author.netid | ReMi818 | - |
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geprüft am 01.06.2024