Derivatives of arsenic substituted phosphorus Chalcogenides

Autor(en): Blachnik, R
Neto, A
Stichwörter: Chemistry; Chemistry, Inorganic & Nuclear; P-31 NMR; TETRAPHOSPHORUS; triphospha arsena trichalcogena diiodide; triphospha arsena trithia diiodomethyl iodide
Erscheinungsdatum: 1997
Herausgeber: JOHANN AMBROSIUS BARTH VERLAG
Journal: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volumen: 623
Ausgabe: 7
Startseite: 1043
Seitenende: 1047
Zusammenfassung: 
alpha-AsP3S3I2, alpha-AsP3Se3I2, and three isomers of beta-AsP3S3I2 were observed besides several phosphorus sulfides by P-31 NMR spectroscopy after the reaction of AsnP4-nE3 (E = S; Se; n = 0-4) with I-2 in the melt or with I-2, PI3, and N-iodosuccinimid in CS2 solutions. The reaction of AsnP4-nS3 with CHI3 in CS2 solution yielded two isomers of beta-AsP3S3(CHI2)I.
ISSN: 00442313
DOI: 10.1002/zaac.19976230706

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