Derivatives of arsenic substituted phosphorus Chalcogenides
Autor(en): | Blachnik, R Neto, A |
Stichwörter: | Chemistry; Chemistry, Inorganic & Nuclear; P-31 NMR; TETRAPHOSPHORUS; triphospha arsena trichalcogena diiodide; triphospha arsena trithia diiodomethyl iodide | Erscheinungsdatum: | 1997 | Herausgeber: | JOHANN AMBROSIUS BARTH VERLAG | Journal: | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | Volumen: | 623 | Ausgabe: | 7 | Startseite: | 1043 | Seitenende: | 1047 | Zusammenfassung: | alpha-AsP3S3I2, alpha-AsP3Se3I2, and three isomers of beta-AsP3S3I2 were observed besides several phosphorus sulfides by P-31 NMR spectroscopy after the reaction of AsnP4-nE3 (E = S; Se; n = 0-4) with I-2 in the melt or with I-2, PI3, and N-iodosuccinimid in CS2 solutions. The reaction of AsnP4-nS3 with CHI3 in CS2 solution yielded two isomers of beta-AsP3S3(CHI2)I. |
ISSN: | 00442313 | DOI: | 10.1002/zaac.19976230706 |
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