Reaction products of diorganotin(IV) oxides, R2SnO, with nitric acid. Part 1: R = methyl, ethyl, and isopropyl

DC FieldValueLanguage
dc.contributor.authorReuter, Hans
dc.contributor.authorReichelt, Martin
dc.date.accessioned2021-12-23T15:59:58Z-
dc.date.available2021-12-23T15:59:58Z-
dc.date.issued2014
dc.identifier.issn00084042
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/4260-
dc.description.abstractThe reaction of diorganotin(IV) oxides, R2SnO with R = Me, Et, and i-Pr, with nitric acid in different stoichiometric ratios resulted in the formation of different products depending on the organic groups. The diorganotin(IV) nitrate hydroxides Me2Sn(NO3)(OH) (1a) Et2Sn(NO3)(OH), alpha-1b, beta-1b, i-Pr2Sn(NO3)(OH) (1c), the diisopropyltin(IV) dinitrate dihydrate, i-Pr2Sn(NO3)(2)center dot 2H(2)O (2c) and the diisopropyltin(IV) nitrate oxalate dihydrate, [i-Pr2Sn(NO3)](2)Ox center dot 2H(2)O (3) as side-product. On examination of the solubility of the primary reaction products in different solvents, the two additional compounds Me2Sn(NO3)(OH)center dot DMSO (4) and 2i-Pr2Sn(NO3)(2)center dot 3DMSO = [i-Pr2Sn(NO3)(dmso)(3)] [i-Pr2Sn(NO3)(3)] (5) have been isolated. All compounds have been structurally characterized by single crystal X-ray diffraction with special respect to dimensionality (1a, alpha-1b, 1c = dimeric molecules hydrogen bonded to one-dimensional chains; beta-1b = two-dimensional coordination polymer; 2c = monomeric; 3 = monomeric, tin atoms linked via a double side-on chelating oxalate ion; 4 = dimeric, 5 = monomeric anion/cation), tin coordination (trigonal-bipyramidal = 1a, alpha-1b, 1c; six-fold = beta-1b; seven-fold = 3, 4, 5-cation; eight-fold = 2c, 5-anion) and nitrate bonding modes (monodentate = 1a, alpha-1b, 1c; unsymmetrical bidentate = 3, symmetrical bidentate = 3, 4, 5-cation, 5-anion; syn-anti bridging = beta-1b), the latter one being analysed using both, Sn-O and N-O distances.
dc.description.sponsorshipDeutsche ForschungsgemeinschaftGerman Research Foundation (DFG); Government of Lower Saxony; University of Osnabruck; We thank the Deutsche Forschungsgemeinschaft and the Government of Lower Saxony for funding the Bruker Kappa APEX II diffractometer. One of the authors (MR) is thankful to the University of Osnabruck for financial support.
dc.language.isoen
dc.publisherCANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS
dc.relation.ispartofCANADIAN JOURNAL OF CHEMISTRY
dc.subjectADDUCTS
dc.subjectChemistry
dc.subjectChemistry, Multidisciplinary
dc.subjectCOMPLEX SALTS
dc.subjectcoordination behavior
dc.subjectCRYSTAL-STRUCTURE
dc.subjectdiorganotin(IV) compounds
dc.subjectDIPHENYLTIN DINITRATE
dc.subjectDIPHOSPHINE
dc.subjecthydrates
dc.subjectLIGANDS
dc.subjectMOLECULAR-STRUCTURE
dc.subjectNITRATE
dc.subjectnitrates
dc.subjectoxalates
dc.subjectSTRUCTURAL-CHARACTERIZATION
dc.subjectstructure determination
dc.subjectstructure types
dc.subjectTIN-OXYGEN INTERACTIONS
dc.titleReaction products of diorganotin(IV) oxides, R2SnO, with nitric acid. Part 1: R = methyl, ethyl, and isopropyl
dc.typejournal article
dc.identifier.doi10.1139/cjc-2013-0513
dc.identifier.isiISI:000343115500007
dc.description.volume92
dc.description.issue6
dc.description.startpage471
dc.description.endpage483
dc.identifier.eissn14803291
dc.publisher.place65 AURIGA DR, SUITE 203, OTTAWA, ON K2E 7W6, CANADA
dcterms.isPartOf.abbreviationCan. J. Chem.
crisitem.author.deptInstitut für Chemie neuer Materialien-
crisitem.author.deptidinstitute11-
crisitem.author.parentorgFB 05 - Biologie/Chemie-
crisitem.author.grandparentorgUniversität Osnabrück-
crisitem.author.netidReHa636-
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