Monoorganotin-polyoxometal compounds - Part 1. Synthesis and crystal structure of [((PrSn)-Pr-i)(11)((VO)-O-IV)O-14(OH)(6)]Cl center dot 2DMF center dot H2O. The first example in a series of monoorganotin-polyoxometal compounds with icosahedral metal arrangement and various contents of tin and vanadium
DC Element | Wert | Sprache |
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dc.contributor.author | Kastner, G | |
dc.contributor.author | Reuter, H | |
dc.date.accessioned | 2021-12-23T16:00:34Z | - |
dc.date.available | 2021-12-23T16:00:34Z | - |
dc.date.issued | 2000 | |
dc.identifier.issn | 0022328X | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/4467 | - |
dc.description.abstract | The synthesis, molecular and crystal structure of the [((PrSn)-Pr-i)(11)(VO)O-14(OH)(6)](+) ion 1 are described. 1 was found in the compound 1.Cl.2DMF.H2O and is the first oxovanadium derivative of the long-known [((PrSn)-Pr-i)(12)O-14(OH)(6)](2+) ion 2. The green compound crystallizes in the triclinic space group P (1) over bar with a = 13.989(2), b = 14.541(2), c = 19.713(3) Angstrom, alpha = 97.16(1)degrees, beta = 93.79(1)degrees, gamma = 116.08(1)degrees, V = 3540.5(9) Angstrom(3), Z = 2. 1 shows the same icosahedral arrangement of metal atoms as the tin compound as well as the same arrangement of oxygen atoms. The vanadium atom is coordinated by five oxygen atoms and replaces one of the square-pyramidally coordinated organotin groups. In the solid state the big cations are linked by hydrogen bonds to Cl- ions forming chains along the a axis. Two of these chains are linked by OH ... O=V hydrogen bonds resulting in a band structure. (C) 2000 Elsevier Science S.A. All rights reserved. | |
dc.language.iso | en | |
dc.publisher | ELSEVIER SCIENCE SA | |
dc.relation.ispartof | JOURNAL OF ORGANOMETALLIC CHEMISTRY | |
dc.subject | BOND-VALENCE PARAMETERS | |
dc.subject | cage ion | |
dc.subject | Chemistry | |
dc.subject | Chemistry, Inorganic & Nuclear | |
dc.subject | Chemistry, Organic | |
dc.subject | crystal structure | |
dc.subject | heteropolyoxometalates | |
dc.subject | HYDROLYSIS | |
dc.subject | tin | |
dc.subject | vanadium | |
dc.title | Monoorganotin-polyoxometal compounds - Part 1. Synthesis and crystal structure of [((PrSn)-Pr-i)(11)((VO)-O-IV)O-14(OH)(6)]Cl center dot 2DMF center dot H2O. The first example in a series of monoorganotin-polyoxometal compounds with icosahedral metal arrangement and various contents of tin and vanadium | |
dc.type | journal article | |
dc.identifier.doi | 10.1016/S0022-328X(99)00738-X | |
dc.identifier.isi | ISI:000086335600025 | |
dc.description.volume | 598 | |
dc.description.issue | 2 | |
dc.description.startpage | 381 | |
dc.description.endpage | 386 | |
dc.contributor.researcherid | H-9847-2014 | |
dc.publisher.place | PO BOX 564, 1001 LAUSANNE, SWITZERLAND | |
dcterms.isPartOf.abbreviation | J. Organomet. Chem. | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | ReHa636 | - |
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