Monoorganotin-polyoxometal-compounds. Part IV: Na-2[((PrSn3)-Pr-i)(OV)(4)O-10(OH)(3)]center dot 5H(2)O center dot 3DMSO, a novel branched tetravanadate(V) stabilized by a trimeric monoorganotin-oxo-hydroxo unit

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dc.contributor.authorReuter, Hans
dc.contributor.authorIzaaryene, Maher
dc.date.accessioned2021-12-23T16:01:05Z-
dc.date.available2021-12-23T16:01:05Z-
dc.date.issued2010
dc.identifier.issn00201693
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/4755-
dc.description.abstractVia self-assembly of the molecular precursors sodium orthovanadate and isopropyltin-dihydroxide-chloride the unprecedented organic-inorganic hybrid polyoxoanion [((PrSn)-Pr-i)(3)(OV)(4)O-10(OH)(3)](2) was synthesized in dimethylsulfoxide (DMSO) and isolated as its sodium salt Na-2[((PrSn)-Pr-i)(3)(OV)(4)O-10(OH)(3)]center dot 5H(2)O center dot 3DMSO. This spherical nanosized anion is composed of two different structural subunits, a well-known trinuclear monoorganotin-polyoxo-hydroxo unit with octahedrally coordinated tin atoms and a new open-chain, branched isopolyoxo tetravanadate(V) with tetrahedrally coordinated vanadium atoms. (C) 2010 Elsevier B. V. All rights reserved.
dc.description.sponsorshipDeutsche ForschungsgemeinschaftGerman Research Foundation (DFG); Government of Lower Saxony; We thank the Deutsche Forschungsgemeinschaft and the Government of Lower Saxony for their financial support in the acquisition of the Bruker Kappa APEX II diffractometer.
dc.language.isoen
dc.publisherELSEVIER SCIENCE SA
dc.relation.ispartofINORGANICA CHIMICA ACTA
dc.subject1ST EXAMPLE
dc.subjectChemistry
dc.subjectChemistry, Inorganic & Nuclear
dc.subjectCRYSTAL-STRUCTURE
dc.subjectHYDROLYSIS
dc.subjectMOLYBDATES
dc.subjectMonoorganotin compounds
dc.subjectMULTIPLE ORGANIC GROUPS
dc.subjectNanoclusters
dc.subjectNMR
dc.subjectOrganic-inorganic hybrid materials
dc.subjectORGANOTIN DERIVATIVES
dc.subjectPolyoxovanadates
dc.subjectVANADATES
dc.subjectX-ray diffraction
dc.titleMonoorganotin-polyoxometal-compounds. Part IV: Na-2[((PrSn3)-Pr-i)(OV)(4)O-10(OH)(3)]center dot 5H(2)O center dot 3DMSO, a novel branched tetravanadate(V) stabilized by a trimeric monoorganotin-oxo-hydroxo unit
dc.typejournal article
dc.identifier.doi10.1016/j.ica.2010.07.055
dc.identifier.isiISI:000284626700020
dc.description.volume363
dc.description.issue15
dc.description.startpage4277
dc.description.endpage4281
dc.contributor.researcheridH-9847-2014
dc.identifier.eissn18733255
dc.publisher.placePO BOX 564, 1001 LAUSANNE, SWITZERLAND
dcterms.isPartOf.abbreviationInorg. Chim. Acta
crisitem.author.deptInstitut für Chemie neuer Materialien-
crisitem.author.deptidinstitute11-
crisitem.author.parentorgFB 05 - Biologie/Chemie-
crisitem.author.grandparentorgUniversität Osnabrück-
crisitem.author.netidReHa636-
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