Monoorganotin-polyoxometal-compounds. Part IV: Na-2[((PrSn3)-Pr-i)(OV)(4)O-10(OH)(3)]center dot 5H(2)O center dot 3DMSO, a novel branched tetravanadate(V) stabilized by a trimeric monoorganotin-oxo-hydroxo unit
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Reuter, Hans | |
dc.contributor.author | Izaaryene, Maher | |
dc.date.accessioned | 2021-12-23T16:01:05Z | - |
dc.date.available | 2021-12-23T16:01:05Z | - |
dc.date.issued | 2010 | |
dc.identifier.issn | 00201693 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/4755 | - |
dc.description.abstract | Via self-assembly of the molecular precursors sodium orthovanadate and isopropyltin-dihydroxide-chloride the unprecedented organic-inorganic hybrid polyoxoanion [((PrSn)-Pr-i)(3)(OV)(4)O-10(OH)(3)](2) was synthesized in dimethylsulfoxide (DMSO) and isolated as its sodium salt Na-2[((PrSn)-Pr-i)(3)(OV)(4)O-10(OH)(3)]center dot 5H(2)O center dot 3DMSO. This spherical nanosized anion is composed of two different structural subunits, a well-known trinuclear monoorganotin-polyoxo-hydroxo unit with octahedrally coordinated tin atoms and a new open-chain, branched isopolyoxo tetravanadate(V) with tetrahedrally coordinated vanadium atoms. (C) 2010 Elsevier B. V. All rights reserved. | |
dc.description.sponsorship | Deutsche ForschungsgemeinschaftGerman Research Foundation (DFG); Government of Lower Saxony; We thank the Deutsche Forschungsgemeinschaft and the Government of Lower Saxony for their financial support in the acquisition of the Bruker Kappa APEX II diffractometer. | |
dc.language.iso | en | |
dc.publisher | ELSEVIER SCIENCE SA | |
dc.relation.ispartof | INORGANICA CHIMICA ACTA | |
dc.subject | 1ST EXAMPLE | |
dc.subject | Chemistry | |
dc.subject | Chemistry, Inorganic & Nuclear | |
dc.subject | CRYSTAL-STRUCTURE | |
dc.subject | HYDROLYSIS | |
dc.subject | MOLYBDATES | |
dc.subject | Monoorganotin compounds | |
dc.subject | MULTIPLE ORGANIC GROUPS | |
dc.subject | Nanoclusters | |
dc.subject | NMR | |
dc.subject | Organic-inorganic hybrid materials | |
dc.subject | ORGANOTIN DERIVATIVES | |
dc.subject | Polyoxovanadates | |
dc.subject | VANADATES | |
dc.subject | X-ray diffraction | |
dc.title | Monoorganotin-polyoxometal-compounds. Part IV: Na-2[((PrSn3)-Pr-i)(OV)(4)O-10(OH)(3)]center dot 5H(2)O center dot 3DMSO, a novel branched tetravanadate(V) stabilized by a trimeric monoorganotin-oxo-hydroxo unit | |
dc.type | journal article | |
dc.identifier.doi | 10.1016/j.ica.2010.07.055 | |
dc.identifier.isi | ISI:000284626700020 | |
dc.description.volume | 363 | |
dc.description.issue | 15 | |
dc.description.startpage | 4277 | |
dc.description.endpage | 4281 | |
dc.contributor.researcherid | H-9847-2014 | |
dc.identifier.eissn | 18733255 | |
dc.publisher.place | PO BOX 564, 1001 LAUSANNE, SWITZERLAND | |
dcterms.isPartOf.abbreviation | Inorg. Chim. Acta | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | ReHa636 | - |
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