TERNARY CHALCOGENIDE SYSTEMS-X - THE QUASITERNARY SYSTEM AG2S-CU2S-P4S10

Autor(en): BLACHNIK, R
GATHER, B
ANDRAE, E
Stichwörter: Chemistry; Chemistry, Analytical; Chemistry, Physical; Thermodynamics
Erscheinungsdatum: 1991
Herausgeber: JOHN WILEY & SONS LTD
Journal: JOURNAL OF THERMAL ANALYSIS
Volumen: 37
Ausgabe: 6
Startseite: 1289
Seitenende: 1298
Zusammenfassung: 
{The quasiternary system Ag2S-Cu2S-P4S10**} was investigated by DTA- and X-ray measurements. No quasiternary compound was found. The phase diagram of the constituent binary Cu2S - P4S10 is given for the first time. It contains the compounds Cu7PS6, Cu3PS4 and (CuPS3)n. The previously reported Cu4P2S7 was not observed. Thermal and X-ray data of these compounds are given. The compounds Cu7PS6 Ag7PS6 and Cu3PS4 Ag3PS4 are completely miscible in the solid state.}
ISSN: 03684466
DOI: 10.1007/BF01913862

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