Photo-Electrochemical Device Enabling Luminescence Switching of LaPO4:Ce,Tb Nanoparticle Layers
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Klein, Jonas | |
dc.contributor.author | Beladi-Mousavi, Seyyed Mohsen | |
dc.contributor.author | Schleutker, Marco | |
dc.contributor.author | Taffa, Dereje Hailu | |
dc.contributor.author | Haase, Markus | |
dc.contributor.author | Walder, Lorenz | |
dc.date.accessioned | 2021-12-23T16:01:33Z | - |
dc.date.available | 2021-12-23T16:01:33Z | - |
dc.date.issued | 2021 | |
dc.identifier.issn | 21951071 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/5030 | - |
dc.description.abstract | The luminescence properties of LaPO4:Ce,Tb nanoparticles are known to depend on the oxidation state of the cerium ions. However, their assembly into thin films exhibiting reasonable fast Ce3+/4+ electrochemistry is not trivial. Herein, the electrochemical luminescence switching of LaPO4:Ce,Tb nanoparticles, assembled as nonconducting thin films, using two electrocatalytic processes, is demonstrated. Due to the insulating nature of these nanoporous films, redox shuttles are used to access the redox active Ce3+/4+ species for electrochemical reactions. A series of redox shuttles with various redox potentials are employed to investigate their capability to electrochemically oxidize Ce3+ within the nanoparticles. Thereby the formal redox potential of the Ce3+/4+ couple in LaPO4:Ce,Tb nanoparticles is determined to lie within 0.89 and 1.15 V versus Ag/AgCl. In situ observation of repetitive luminescence switching is realized by assembling a device that allows UV light to enter the nanoparticle layer. With two redox shuttles present in the electrolyte, one for the oxidation of Ce3+ and the other for reduction of Ce4+, quenching and restoration of the luminescence is monitored. The resulting device represents the first down-sizable logical AND gate with UV light and voltage inputs and a vis light output based on a solid state LaPO4:Ce,Tb layer. | |
dc.description.sponsorship | Projekt DEAL; Open access funding enabled and organized by Projekt DEAL. | |
dc.language.iso | en | |
dc.publisher | WILEY-V C H VERLAG GMBH | |
dc.relation.ispartof | ADVANCED OPTICAL MATERIALS | |
dc.subject | BEHAVIOR | |
dc.subject | CE3+ | |
dc.subject | CORE | |
dc.subject | electrochemistry | |
dc.subject | ENERGY-TRANSFER | |
dc.subject | lanthanides | |
dc.subject | logic gates | |
dc.subject | luminescence switching | |
dc.subject | Materials Science | |
dc.subject | Materials Science, Multidisciplinary | |
dc.subject | Optics | |
dc.subject | OVERCHARGE | |
dc.subject | PROTECTION | |
dc.subject | redox mediators | |
dc.subject | REDOX REACTION | |
dc.subject | TB3+ | |
dc.subject | VISIBLE-LIGHT | |
dc.title | Photo-Electrochemical Device Enabling Luminescence Switching of LaPO4:Ce,Tb Nanoparticle Layers | |
dc.type | journal article | |
dc.identifier.doi | 10.1002/adom.202001891 | |
dc.identifier.isi | ISI:000601104400001 | |
dc.description.volume | 9 | |
dc.description.issue | 5 | |
dc.contributor.orcid | 0000-0002-9686-8810 | |
dc.publisher.place | POSTFACH 101161, 69451 WEINHEIM, GERMANY | |
dcterms.isPartOf.abbreviation | Adv. Opt. Mater. | |
dcterms.oaStatus | hybrid | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.orcid | 0000-0002-9686-8810 | - |
crisitem.author.orcid | 0000-0002-5497-034X | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | HaMa954 | - |
crisitem.author.netid | WaLo966 | - |
Seitenaufrufe
3
Letzte Woche
0
0
Letzter Monat
1
1
geprüft am 01.06.2024