Tin halogen compounds. 3. Recent data on crystal and molecular structure of dimethyl tin dichloride

DC FieldValueLanguage
dc.contributor.authorReuter, H
dc.contributor.authorPawlak, R
dc.date.accessioned2021-12-23T16:01:41Z-
dc.date.available2021-12-23T16:01:41Z-
dc.date.issued2001
dc.identifier.issn00442968
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/5103-
dc.description.abstractThe crystal structure of dimethyltin dichloride, Me2SnCl2, known for a long time, has been corrected by means of four-circle diffractometer data, because in comparison to other diorganotin dichlorides serious doubts about the molecular geometry came up. The new, corrected values confirm the old structure model but supply more reliable data in view of the molecular parameters. In particular, the following values have been found for distances and angles: d(Sn-C) = 212.0(7) pm, d(Sn-Cl)= 238.9(2)pm, angle (Cl-Sn-Cl) = 98.60(9)degrees, angle (C-Sn-C) = 142.2(4)degrees. The length of the intermolecular tin . . . chlorine bridge was determined to 343.3 pm. This value shows that dimethyltin dichloride has a strong intermolecular association due to small sterical shielding of the tin atom by the methyl groups.
dc.language.isode
dc.publisherR OLDENBOURG VERLAG
dc.relation.ispartofZEITSCHRIFT FUR KRISTALLOGRAPHIE
dc.subjectCrystallography
dc.titleTin halogen compounds. 3. Recent data on crystal and molecular structure of dimethyl tin dichloride
dc.typejournal article
dc.identifier.doi10.1524/zkri.216.1.56.18994
dc.identifier.isiISI:000166646900010
dc.description.volume216
dc.description.issue1
dc.description.startpage56
dc.description.endpage59
dc.contributor.researcheridH-9847-2014
dc.publisher.placeLEKTORAT M/N, K BERBER-NERLINGER, POSTFACH 80 13 60, D-81613 MUNICH, GERMANY
dcterms.isPartOf.abbreviationZ. Kristall.
crisitem.author.deptInstitut für Chemie neuer Materialien-
crisitem.author.deptidinstitute11-
crisitem.author.parentorgFB 05 - Biologie/Chemie-
crisitem.author.grandparentorgUniversität Osnabrück-
crisitem.author.netidReHa636-
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