Crystal structure of 1,1 `-dimethyl-4,4 `-bipyridinium-octachlorodiantimonate(III)

Autor(en): Jaschinski, B
Blachnik, R
Reuter, H 
Stichwörter: Chemistry; Chemistry, Inorganic & Nuclear; Chemistry, Organic; crystal structure 1,1 `-dimethyl-4,4 `-bipyridinium-octachlorodiantimonate(III)
Erscheinungsdatum: 1998
Herausgeber: VERLAG Z NATURFORSCH
Journal: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Volumen: 53
Ausgabe: 5-6
Startseite: 565
Seitenende: 568
Zusammenfassung: 
The title compound was prepared by reaction of SbCl3 with 1,1'-dimethyl-4,4'-bipyridinium-chloride in methanol. The single crystal structure gave the following data: [C12H14N2][Sb2Cl8] (1) space group P1, Nr. 1, with a = 570.68(7) pm, b = 938.57(14) pm, c = 1174.27(11) pm, alpha = 66.72(9)degrees, beta = 89.304(12)degrees, gamma = 78.684(11)degrees, and Z = 1. The compound has a small SHG effect and a phase transition at 272 degrees C with an enthalpy of transition of 6.54 kJ mol(-1).
ISSN: 09320776
DOI: 10.1515/znb-1998-5-613

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