NEW A4B3 MOLECULES - P3SBS3, P4S2TE AND P4STE2
Autor(en): | BALDUS, HP BLACHNIK, R |
Stichwörter: | Chemistry; Chemistry, Inorganic & Nuclear; Chemistry, Organic; LATTICE PARAMETERS OF P3SBS3; P-31; P-31 NMR SPECTRA; PHOSPHORUS ANTIMONY SULFIDE; PHOSPHORUS SULFIDE TELLURIDE; SYSTEM | Erscheinungsdatum: | 1990 | Herausgeber: | VERLAG Z NATURFORSCH | Journal: | ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | Volumen: | 45 | Ausgabe: | 12 | Startseite: | 1605 | Seitenende: | 1609 | Zusammenfassung: | The new molecules P3SbS3, P4S2Te2 und P4STe2 were extracted with CS2 from mixtures of S. Sb and P4S3, and P, S and Te samples respectively, which were previously molten and then annealed for several days. In the P3SbS3 molecules the apical phosphorus position of P4S3 is substituted by antimony. In the molecules P4STe2 and P4S2Te one or two of the sulphur bridges are substituted by tellurium. X-ray and P-31 NMR data of the compounds are given. |
ISSN: | 09320776 | DOI: | 10.1515/znb-1990-1201 |
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