The high-anti conformation of 8-aza-1,3-dideaza-2 `-deoxyadenosine

DC FieldValueLanguage
dc.contributor.authorSeela, F
dc.contributor.authorHe, Y
dc.contributor.authorReuter, H
dc.contributor.authorHeithoff, EM
dc.date.accessioned2021-12-23T16:02:44Z-
dc.date.available2021-12-23T16:02:44Z-
dc.date.issued2001
dc.identifier.issn01082701
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/5587-
dc.description.abstractIn the title compound, 4-amino-1-(2-deoxy-beta -D-erythro-pentofuranosyl)-1H-benzotriazole, C11H14N4O3, the conformation of the N-glycosidic bond is in the high-anti range [chi = - 77.1 (4)degrees] and the 2'-deoxyribofuranose moiety adopts a 2'-endo ( (2) E) sugar puckering. The 5'-hydroxyl group is disordered and has conformations ap with gamma = 171.1 (3)degrees [occupation of 61.4 (3)%] and sc with gamma = 52.4 (6)degrees [occupation of 38.6 (3)%]. The nucleobases are stacked in the crystal state.
dc.language.isoen
dc.publisherMUNKSGAARD INT PUBL LTD
dc.relation.ispartofACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
dc.subjectChemistry
dc.subjectChemistry, Multidisciplinary
dc.subjectCRYSTAL-STRUCTURE
dc.subjectCrystallography
dc.titleThe high-anti conformation of 8-aza-1,3-dideaza-2 `-deoxyadenosine
dc.typejournal article
dc.identifier.doi10.1107/S0108270101004152
dc.identifier.isiISI:000168798000059
dc.description.volume57
dc.description.issue5
dc.description.startpage660
dc.description.endpage662
dc.contributor.researcheridH-9847-2014
dc.publisher.place35 NORRE SOGADE, PO BOX 2148, DK-1016 COPENHAGEN, DENMARK
dcterms.isPartOf.abbreviationActa Crystallogr. Sect. C-Cryst. Struct. Commun.
crisitem.author.deptInstitut für Chemie neuer Materialien-
crisitem.author.deptidinstitute11-
crisitem.author.parentorgFB 05 - Biologie/Chemie-
crisitem.author.grandparentorgUniversität Osnabrück-
crisitem.author.netidReHa636-
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