Synthesis and structural characterization of a dimeric N,N-dimethylformamide solvate of isobutyltin(IV) dichloride hydroxide, [iBuSnCl(2)(OH)(DMF)](2)
| Autor(en): | Reuter, Hans Ye, Fei |
Stichwörter: | Chemistry; Chemistry, Inorganic & Nuclear; Chemistry, Organic; crystal structure; CRYSTAL-STRUCTURE; HYDROLYSIS; organotin compounds; synthesis; TIN | Erscheinungsdatum: | 2013 | Herausgeber: | WALTER DE GRUYTER GMBH | Journal: | MAIN GROUP METAL CHEMISTRY | Volumen: | 36 | Ausgabe: | 5-6 | Startseite: | 225 | Seitenende: | 227 | Zusammenfassung: | The title compound, isobutyltin(IV) dichloride hydroxide N,N-dimethylformamide solvate {[iBuSnCl(2)(OH)(DMF)](2)}, an accidental side product from the reaction of isobutyltin(IV) trichloride with moisture in N,N-dimethylformamide, exhibits structural features similar to those of the corresponding hydrates of monoorganotin(IV) dihalide hydroxides characterized by a central four-membered rhombic Sn-O ring and tin atoms with a distorted octahedral coordination. |
ISSN: | 07921241 | DOI: | 10.1515/mgmc-2013-0037 |
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