Synthesis and structural characterization of a dimeric N,N-dimethylformamide solvate of isobutyltin(IV) dichloride hydroxide, [iBuSnCl(2)(OH)(DMF)](2)

Autor(en): Reuter, Hans 
Ye, Fei
Stichwörter: Chemistry; Chemistry, Inorganic & Nuclear; Chemistry, Organic; crystal structure; CRYSTAL-STRUCTURE; HYDROLYSIS; organotin compounds; synthesis; TIN
Erscheinungsdatum: 2013
Herausgeber: WALTER DE GRUYTER GMBH
Journal: MAIN GROUP METAL CHEMISTRY
Volumen: 36
Ausgabe: 5-6
Startseite: 225
Seitenende: 227
Zusammenfassung: 
The title compound, isobutyltin(IV) dichloride hydroxide N,N-dimethylformamide solvate {[iBuSnCl(2)(OH)(DMF)](2)}, an accidental side product from the reaction of isobutyltin(IV) trichloride with moisture in N,N-dimethylformamide, exhibits structural features similar to those of the corresponding hydrates of monoorganotin(IV) dihalide hydroxides characterized by a central four-membered rhombic Sn-O ring and tin atoms with a distorted octahedral coordination.
ISSN: 07921241
DOI: 10.1515/mgmc-2013-0037

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