Synthesis and thermal behaviour of compounds in the system [Ph4P]Cl/BiCl3 and the crystal structures of [Ph4P](3)[Bi2Cl9]center dot 2 CH2Cl2 and [Ph4P](2)[Bi2Cl8]center dot 2 CH3COCH3

DC FieldValueLanguage
dc.contributor.authorAhmed, IA
dc.contributor.authorBlachnik, R
dc.contributor.authorReuter, H
dc.date.accessioned2021-12-23T16:03:19Z-
dc.date.available2021-12-23T16:03:19Z-
dc.date.issued2001
dc.identifier.issn00442313
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/5925-
dc.description.abstractSix polynuclear chlorobismuthates are formed in the reaction between BiCl3 and Ph4PCl by variation of the molar ratio of the educts, the solvents and the crystallisation methods: [Ph4P](3)[Bi2Cl9].2 CH2Cl2, [Ph4P](3)[Bi2Cl9]. CH3COCH3, [Ph4Ph](2)[Bi2Cl9] . 2 CH3COCH3, [Ph4P](4)[Bi4Cl16] . 3 CH3CN, [Ph4P](4)[Bi6Cl22]. and [Ph4P](4)[Bi8Cl28]. We report the crystal structure of [Ph4P]3[Bi2Cl9] . 2 CH2Cl2 which crystallises with triclinic symmetry in the S. G. P (1) over bar No. 2, with the lattice parameters a = 13.080(3) Angstrom, b 14.369(3) Angstrom. c = 21.397(4) Angstrom, alpha = 96.83(l)degrees, beta = 95.96(l)degrees, gamma = 95.94(2)degrees, V = 3943.9(l) Angstrom (3), Z = 2. The anion is formed from two face-sharing BiCl6-octahedra. [Ph4P](2)[Bi2Cl8] . 2 CH3COCH3 crystallises with monoclinic symmetry in the S; G. P2(1)/n, No. 14, with the lattice parameters a = 14.045(5) Angstrom, b = 12.921(4) Angstrom, c = 17.098(3) Angstrom. beta = 111. 10(2)degrees, V = 2894.8(2) Angstrom (3). Z = 2. The anion is a bi-octahedron of two square-pyramids, joined by a common edge. The octahedral coordination is achieved with two acetone ligands. [Ph4P](4)[Bi4Cl16] . 3CH(3)CN crystallises in the triclinic S. G., P (1) over bar, No. 2, with the lattice parameters a = 14.245(9) Angstrom, b = 17.318(6)Angstrom, c = 24.475(8) Angstrom. alpha = 104.66(3)degrees, beta = 95.93(3)degrees, gamma = 106.90(4)degrees. V = 5486(4) Angstrom (3), Z = 2. Two Bi2Cl8 dimers in syn-position form the cubic anion. Lattice parameters of [Ph4P](3)[Bi2Cl9] . CH3COCH3 are also given. The solvated compounds are desolvated at approximately 100 degreesC. [Ph4P](3)[Bi2Cl9] . 2CH(2)Cl(2) and [Ph4P](3)[Bi2Cl9] . CH3COCH3 show the same sequence of phase transitions after desolvation. All compounds melt into a liquid in which some order is observed and transform on cooling into the glassy state.
dc.language.isoen
dc.publisherWILEY-V C H VERLAG GMBH
dc.relation.ispartofZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
dc.subjectANIONS
dc.subjectBISMUTH(III)
dc.subjectbismuth(III) chloride
dc.subjectChemistry
dc.subjectChemistry, Inorganic & Nuclear
dc.subjectchlorobismuthates
dc.subjectCOMPLEXES
dc.subjectcrystal structure
dc.subjecttetraphenylphosphonium chloride
dc.subjectthermal analysis
dc.titleSynthesis and thermal behaviour of compounds in the system [Ph4P]Cl/BiCl3 and the crystal structures of [Ph4P](3)[Bi2Cl9]center dot 2 CH2Cl2 and [Ph4P](2)[Bi2Cl8]center dot 2 CH3COCH3
dc.typejournal article
dc.identifier.doi10.1002/1521-3749(200109)627:9<2057::AID-ZAAC2057>3.0.CO;2-7
dc.identifier.isiISI:000171339000007
dc.description.volume627
dc.description.issue9
dc.description.startpage2057
dc.description.endpage2062
dc.contributor.researcheridH-9847-2014
dc.publisher.placePO BOX 10 11 61, D-69451 BERLIN, GERMANY
dcterms.isPartOf.abbreviationZ. Anorg. Allg. Chem.
crisitem.author.deptInstitut für Chemie neuer Materialien-
crisitem.author.deptidinstitute11-
crisitem.author.parentorgFB 05 - Biologie/Chemie-
crisitem.author.grandparentorgUniversität Osnabrück-
crisitem.author.netidReHa636-
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