2 `-Deoxy-5-fluorotubercidin
Autor(en): | Seela, F Xu, KY Eickmeier, H |
Stichwörter: | Chemistry; Chemistry, Multidisciplinary; Crystallography | Erscheinungsdatum: | 2005 | Herausgeber: | INT UNION CRYSTALLOGRAPHY | Journal: | ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | Volumen: | 61 | Ausgabe: | 6 | Startseite: | O408-O410 | Zusammenfassung: | In the title compound, 4- amino- 7-( 2- deoxy-beta-D-erythro- pentofuranosyl)-5- fluoro- 7H- pyrrolo[ 2,3- d] pyrimidine, C11H13FN4O3, the conformation of the glycosyl bond lies between anti and high anti [ chi = - 101.1 ( 3)degrees]. The furanose moiety adopts the S- type sugar pucker ( T-2(3)), with P = 164.7 ( 3)degrees and tau = 40.1 (2)degrees. The extended structure is a three- dimensional hydrogen- bond network involving a C - H center dot center dot center dot F, two N - H center dot center dot center dot O and two O - H center dot center dot center dot O hydrogen bonds. |
ISSN: | 20532296 | DOI: | 10.1107/S0108270105014265 |
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geprüft am 21.05.2024