DC Element | Wert | Sprache |
dc.contributor.author | Reuter, Hans | |
dc.date.accessioned | 2023-02-17T11:31:25Z | - |
dc.date.available | 2023-02-17T11:31:25Z | - |
dc.date.issued | 2022 | |
dc.identifier.issn | 2056-9890 | |
dc.identifier.uri | http://osnascholar.ub.uni-osnabrueck.de/handle/unios/65257 | - |
dc.description.abstract | The crystal structure of di-tert-butylhydroxidoiodidotin(IV), [Sn(C4H9)(2)I(OH)] or (Bu2Sn)-Bu-t(OH)I, consists of dimeric, centrosymmetric molecules exhibiting the typical structural features of diorganotin(IV)-hydroxide-halides, R2Sn(OH)Hal. Two trigonal-bipyramidally coordinated tin(IV) atoms are bridged via two hydroxyl groups, resulting in a planar, four-membered Sn-O(2) ring of rhombic shape, with acute angles at tin, obtuse angles at oxygen and two different Sn-O distances depending whether the oxygen atom adopts an axial or equatorial position at the tin(IV) atom. In contrast to its fluorine, chlorine and bromine homologues, no hydrogen bonds between the OH group and the halide atom exist, confining the intermolecular interactions to van der Waals forces. | |
dc.description.sponsorship | Deutsche Forschungsgemeinschaft; Government of Lower-Saxony; Deutsche Forschungsgemeinschaft (DFG); Open Access Publishing Fund of Osnabruck University; The author thanks the Deutsche Forschungsgemeinschaft and the Government of Lower-Saxony for funding the diffractometer and acknowledge support by the Deutsche Forschungsgemeinschaft (DFG) and the Open Access Publishing Fund of Osnabruck University. | |
dc.language.iso | en | |
dc.publisher | INT UNION CRYSTALLOGRAPHY | |
dc.relation.ispartof | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | |
dc.subject | COMPLEXES | |
dc.subject | crystal structure | |
dc.subject | CRYSTAL-STRUCTURE | |
dc.subject | Crystallography | |
dc.subject | DIHALIDES | |
dc.subject | HYDROLYSIS | |
dc.subject | trigonalbipyramidal coordination | |
dc.subject | van-der-Waals interaction | |
dc.title | Di-tert-butyltin(IV)-hydroxide-iodide, (Bu2Sn)-Bu-t(OH)I, the last missing member in the series of pure di-tert-butyltin(IV)-hydroxide-halides | |
dc.type | journal article | |
dc.identifier.doi | 10.1107/S205698902200514X | |
dc.identifier.isi | ISI:000851387700019 | |
dc.description.volume | 78 | |
dc.description.issue | 6 | |
dc.description.startpage | 633+ | |
dc.publisher.place | 2 ABBEY SQ, CHESTER, CH1 2HU, ENGLAND | |
dcterms.isPartOf.abbreviation | Acta Crystallogr. Sect. E.-Crystallogr. Commun. | |
dcterms.oaStatus | gold, Green Published | |
local.import.remains | affiliations : University Osnabruck | |
local.import.remains | web-of-science-index : Emerging Sources Citation Index (ESCI) | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | ReHa636 | - |