BaTiO3 and Ba0.77Ca0.27TiO3 doped with Rhodium: quantitative determination of charge transfer parameters by EPR-based defect studies

Autor(en): Meyer, M.
Veber, C.
Schirmer, O.F.
Malovichko, G.I.
Grachev, V.G.
Kaczmarek, M.
Stichwörter: Calcium compounds; Charge transfer; Paramagnetic resonance; Photoreactivity, Defect study; Electrooptic materials; Performance; Photorefractives; Property; Quantitative determinations; Sensitive materials; Transfer parameters, Defects
Erscheinungsdatum: 2003
Herausgeber: Optica Publishing Group (formerly OSA)
Journal: Optics InfoBase Conference Papers
Startseite: 124
Seitenende: 129
Zusammenfassung: 
A detailed knowledge about the defects in an electro-optic material is necessary to understand and steer its photorefractive performance. If applicable, electron paramagnetic resonance (EPR) can furnish the most detailed information about many properties of defects. With the infrared sensitive materials BaTiO3 and Ba0.77Ca0.23TiO3, both doped with rhodium, we shall exemplify how the defect related charge transfer parameters can be determined on this basis. They allow to predict the photorefractive behavior of the materials. All these data are derived from EPR-based defect studies alone. © 2003 OSA/PEMD 2003.
Beschreibung: 
Conference of Photorefractive Effects, Materials, and Devices, PR 2003 ; Conference Date: 17 June 2003; Conference Code:181411
ISBN: 9781557527554
Externe URL: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85135927479&partnerID=40&md5=bae2889a7bbf89791a7dc63ecd9d5cb4

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