Transition Metal Compounds Towards Holography

Autor(en): Dieckmann, Volker
Eicke, Sebastian
Springfeld, Kristin
Imlau, Mirco 
Stichwörter: applications; Chemistry; Chemistry, Physical; CRYSTALS; holographic recording materials; INFORMATION-STORAGE; ISOMERIZATION; Materials Science; Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering; METASTABLE ELECTRONIC STATES; NITROSYL-LINKAGE ISOMERS; nonlinear optics; PHOTOCHEMISTRY; PHOTOPHYSICS; Physics; Physics, Applied; Physics, Condensed Matter; RUTHENIUM; SULFOXIDE COMPLEXES; transition metal compounds; WAVE-GUIDES
Erscheinungsdatum: 2012
Herausgeber: MDPI
Journal: MATERIALS
Volumen: 5
Ausgabe: 6
Startseite: 1155
Seitenende: 1175
Zusammenfassung: 
We have successfully proposed the application of transition metal compounds in holographic recording media. Such compounds feature an ultra-fast light-induced linkage isomerization of the transition-metal-ligand bond with switching times in the sub-picosecond regime and lifetimes from microseconds up to hours at room temperature. This article highlights the photofunctionality of two of the most promising transition metal compounds and the photophysical mechanisms that are underlying the hologram recording. We present the latest progress with respect to the key measures of holographic media assembled from transition metal compounds, the molecular embedding in a dielectric matrix and their impressive potential for modern holographic applications.
ISSN: 19961944
DOI: 10.3390/ma5061155

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