S 2p excitation and fragmentation of sulfur aggregates
Autor(en): | Teodorescu, CM Gravel, D Ruhl, E |
Stichwörter: | ABSORPTION-SPECTRA; ARGON CLUSTERS; Chemistry; Chemistry, Physical; COINCIDENCE PEPIPICO TECHNIQUE; CORE-IONIZATION; DOUBLE PHOTOIONISATION; INNER-SHELL EXCITATION; K-EDGE; PHOTOELECTRON-SPECTROSCOPY; Physics; Physics, Atomic, Molecular & Chemical; POST-COLLISION INTERACTION; TRIPLE COINCIDENCE | Erscheinungsdatum: | 1998 | Herausgeber: | AMER INST PHYSICS | Journal: | JOURNAL OF CHEMICAL PHYSICS | Volumen: | 109 | Ausgabe: | 21 | Startseite: | 9280 | Seitenende: | 9287 | Zusammenfassung: | Synchrotron radiation from the storage ring BESSY-I is used to excite the S 2p regime (150-190 eV) of sulfur aggregates S-n, n = 2-8. Valence states are identified in photoion yield spectra of mass selected S-n(+) cations in combination with extended Huckel calculations. Mass spectra, partial ion yields, and photoelectron-photoion-photoion (PEPIPICO) coincidence spectra an reported, yielding a consistent picture of massive decay processes occurring in the S 2p regime. PEPIPICO spectra especially give detailed information on the fragmentation mechanisms of doubly charged aggregates. It is shown that most cation pairs are formed via charge separation originating from S-8(++). We derive values for the kinetic energy releases in multistep fragmentations assuming that charge separation is driven by Coulomb explosion. (C) 1998 American Institute of Physics. [S0021-9606(98)00245-1]. |
ISSN: | 00219606 | DOI: | 10.1063/1.477589 |
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