Amino derivatives of alpha-P4S3, alpha-P4Se3, and P3Se4; data and analyses of their P-31 NMR spectra in solution
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Lutz, J | |
dc.contributor.author | Nowottnick, H | |
dc.contributor.author | Blachnik, R | |
dc.date.accessioned | 2021-12-23T16:05:08Z | - |
dc.date.available | 2021-12-23T16:05:08Z | - |
dc.date.issued | 1999 | |
dc.identifier.issn | 00442313 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/6802 | - |
dc.description.abstract | alpha-P4S3I2, alpha-P4Se3I2, and P3Se4I were reacted with primary and secondary amines in CS2. The reaction yields exo-exo isomeres of alpha-P3S3L2 and alpha-P4Se3L2, the N-bridged compounds alpha-P4S3L' and P3Se4L, with L = NHR1, NPhR2 THC (R-1 = `Bu, Ad, Ph, Flu, TPMP; R-2 = Me, Et, Pr-i), and L'=NR1. The P-31 NMR data of the compounds in CS2 solution were measured. By the reaction of alpha-P4Se3I2 With primary amines NH2'Bu and NH(2)Ad in CS2 an asymmetric isomer alpha-P(4)Se(3)Iendo(NHR1)exo was observed for the first time in the 31P NMR spectra. The influence of the ligands L on the P-31 NMR parameter of alpha-P4S3L2, alpha-P3Se3L2, and P3Se4L is discussed. | |
dc.language.iso | de | |
dc.publisher | WILEY-V C H VERLAG GMBH | |
dc.relation.ispartof | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | |
dc.subject | 2,5-diamino-1,2,4,5-tetraphospha-3,6,7-trichalcogena-bicyclo[2.2.1]hep tan | |
dc.subject | 2-amino-1,2,4-triphospha-3,5,6,7-tetraselena- | |
dc.subject | 8-alkyl-8-aza-1,2,3,5-tetraphospha-3,6,7-trithia-tricyclo[2.2.1.1(2,5) ]octan | |
dc.subject | bicyclo [2.2.1]heptan | |
dc.subject | Chemistry | |
dc.subject | Chemistry, Inorganic & Nuclear | |
dc.subject | MAGNETIC-RESONANCE PARAMETERS | |
dc.subject | P-31 NMR | |
dc.subject | phosphorus chalcogenides | |
dc.subject | SKELETON | |
dc.subject | SUBSTITUENT CONSTANTS | |
dc.subject | TETRAPHOSPHORUS TRISULFIDE COMPOUNDS | |
dc.title | Amino derivatives of alpha-P4S3, alpha-P4Se3, and P3Se4; data and analyses of their P-31 NMR spectra in solution | |
dc.type | journal article | |
dc.identifier.doi | 10.1002/(SICI)1521-3749(199906)625:6<1019::AID-ZAAC1019>3.3.CO;2-0 | |
dc.identifier.isi | ISI:000080696300027 | |
dc.description.volume | 625 | |
dc.description.issue | 6 | |
dc.description.startpage | 1019 | |
dc.description.endpage | 1024 | |
dc.publisher.place | MUHLENSTRASSE 33-34, D-13187 BERLIN, GERMANY | |
dcterms.isPartOf.abbreviation | Z. Anorg. Allg. Chem. |
Seitenaufrufe
3
Letzte Woche
0
0
Letzter Monat
2
2
geprüft am 08.06.2024