Monoorganotin-polyoxometal-compounds:: II.: Isolation and structural characterization of compounds containing the unprecedented monoorganotin molybdate anion [(RSn)4(MoO4)4O(OH)3] -

Monoorganotin-polyoxometal-compounds:: II.: Isolation and structural characterization of compounds containing the unprecedented monoorganotin molybdate anion [(RSn)₄(MoO₄)₄O(OH)₃]^-

Autor(en):	Kastner, G Reuter, H
Stichwörter:	Chemistry; Chemistry, Inorganic & Nuclear; Chemistry, Organic; CRYSTAL-STRUCTURE; HYDROLYSIS; MOLECULAR-STRUCTURE; SOLID-STATE; TIN(IV) ALKOXIDE COMPOUNDS; TRIHALIDES
Erscheinungsdatum:	2000
Herausgeber:	FREUND PUBLISHING HOUSE LTD
Journal:	MAIN GROUP METAL CHEMISTRY
Volumen:	23
Ausgabe:	7
Startseite:	383
Seitenende:	388
Zusammenfassung:	The syntheses, molecular and crystal structures of [((PrSn)-Pr-i)(12)O-14(OH)(6)] [((PrSn)-Pr-i)(4)(MoO4)(4)O(OH)(3)](2) . 6DMSO (1) under bar and [((PrSn)-Pr-i)(12)O-14(OH)(6)] [((PrSn)-Pr-i)(4)(MoO4)(4)O(OH)(3)](2) . 10DMF (2) under bar are described. Both compounds contain the until now unknown [((PrSn)-Pr-i)(4)(MoO4)(4)O(OH)(3)](-) cage ion, the first example of monoorganotin molybdates with isolated anions. It is composed of two groups of two edge sharing (PrSnO5)-Pr-i octahedra linked by four mu(3)-MoO4 tetrahedra. Inside this cage ion a mu(2)-OH ...mu(2)-O hydrogen bond between the two groups of (PrSnO4)-Pr-i(OH) double octahedra is observed.
ISSN:	0334-7575

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