The insertion of chalcogen atoms into the In-In bond of tetrakis[bis(trimethylsilyl)methyl]diindane(4): Monomeric compounds with In-S-In, In-Se-In, and In-Te-In groups

DC FieldValueLanguage
dc.contributor.authorUhl, W
dc.contributor.authorGraupner, R
dc.contributor.authorReuter, H
dc.date.accessioned2021-12-23T16:07:11Z-
dc.date.available2021-12-23T16:07:11Z-
dc.date.issued1996
dc.identifier.issn0022328X
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/7745-
dc.description.abstractThe insertion of chalcogen atoms into the indium-indium bond of tetrakis[bis(trimethylsilyl)methyl]diindane(4) (1) by the reaction of 1 with the chalcogen atom donors propylene sulphide, triethyl phosphonium selenide or telluride yields homoleptic compounds with up to now unknown R(2)In-S-InR(2) (2), R(2)In-Se-InR(2) (3), and R(2)In-Te-InR(2) (4) groups. All products are monomeric, both in solution and in the solid state, as shown by the cryoscopically determined molar masses and crystal structure determinations, The indium-chalcogen-indium bridges are bent and exhibit angles of 112.4(1) and 116.8(2)degrees (2), 109.96(3)degrees (3), and 105.42(2)degrees (4).
dc.language.isoen
dc.publisherELSEVIER SCIENCE SA LAUSANNE
dc.relation.ispartofJOURNAL OF ORGANOMETALLIC CHEMISTRY
dc.subjectAL-AL BOND
dc.subjectALUMINUM ALUMINUM BOND
dc.subjectchalcogen insertion
dc.subjectChemistry
dc.subjectChemistry, Inorganic & Nuclear
dc.subjectChemistry, Organic
dc.subjectCOMPLEXES
dc.subjectCRYSTAL-STRUCTURES
dc.subjectE = S
dc.subjectINDIUM CHALCOGENIDES
dc.subjectindium-indium bond
dc.subjectindium-selenium bond
dc.subjectindium-sulphur bond
dc.subjectindium-tellurium bond
dc.subjectMOLECULAR-STRUCTURE
dc.subjectPOTENTIAL PRECURSORS
dc.subjectR(2)AL-ALR(2) R=CH(SIME(3))(2)
dc.subjectSINGLE
dc.titleThe insertion of chalcogen atoms into the In-In bond of tetrakis[bis(trimethylsilyl)methyl]diindane(4): Monomeric compounds with In-S-In, In-Se-In, and In-Te-In groups
dc.typejournal article
dc.identifier.doi10.1016/0022-328X(96)06392-9
dc.identifier.isiISI:A1996VJ48000014
dc.description.volume523
dc.description.issue2
dc.description.startpage227
dc.description.endpage234
dc.contributor.researcheridH-9847-2014
dc.publisher.placePO BOX 564, 1001 LAUSANNE 1, SWITZERLAND
dcterms.isPartOf.abbreviationJ. Organomet. Chem.
crisitem.author.deptInstitut für Chemie neuer Materialien-
crisitem.author.deptidinstitute11-
crisitem.author.parentorgFB 05 - Biologie/Chemie-
crisitem.author.grandparentorgUniversität Osnabrück-
crisitem.author.netidReHa636-
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