A NOVEL PHOSPHORUS CHALCOGENIDE - P2SE5
| Autor(en): | BLACHNIK, R BALDUS, HP LONNECKE, P TATTERSHALL, BW |
Stichwörter: | Chemistry; Chemistry, Multidisciplinary; CONSTANTS; P-31; PARAMETERS; TRISULFIDE | Erscheinungsdatum: | 1991 | Herausgeber: | VCH PUBLISHERS INC | Journal: | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | Volumen: | 30 | Ausgabe: | 5 | Startseite: | 605 | Seitenende: | 607 | Zusammenfassung: | A phosphorus/selenium ratio of 2:5 does not necessarily mean that P2Se5 is also a structural analogue of P4O10. As shown on the right, the phosphorus atoms in P2Se5 are threefold coordinated. They are joined through one mono- and two diselenide bridges. In short, a large ratio of selenium in the system phosphorus-selenium does not lead automatically to an increase in the coordination number at phosphorus. |
ISSN: | 05700833 | DOI: | 10.1002/anie.199106051 |
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