A NOVEL PHOSPHORUS CHALCOGENIDE - P2SE5

Autor(en): BLACHNIK, R
BALDUS, HP
LONNECKE, P
TATTERSHALL, BW
Stichwörter: Chemistry; Chemistry, Multidisciplinary; CONSTANTS; P-31; PARAMETERS; TRISULFIDE
Erscheinungsdatum: 1991
Herausgeber: VCH PUBLISHERS INC
Journal: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH
Volumen: 30
Ausgabe: 5
Startseite: 605
Seitenende: 607
Zusammenfassung: 
A phosphorus/selenium ratio of 2:5 does not necessarily mean that P2Se5 is also a structural analogue of P4O10. As shown on the right, the phosphorus atoms in P2Se5 are threefold coordinated. They are joined through one mono- and two diselenide bridges. In short, a large ratio of selenium in the system phosphorus-selenium does not lead automatically to an increase in the coordination number at phosphorus.
ISSN: 05700833
DOI: 10.1002/anie.199106051

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