ADSORPTION AND REACTION ON OXIDE SURFACES - CO AND CO2 ON CR2O3(111)

DC FieldValueLanguage
dc.contributor.authorKUHLENBECK, H
dc.contributor.authorXU, C
dc.contributor.authorDILLMANN, B
dc.contributor.authorHASSEL, M
dc.contributor.authorADAM, B
dc.contributor.authorEHRLICH, D
dc.contributor.authorWOHLRAB, S
dc.contributor.authorFREUND, HJ
dc.contributor.authorDITZINGER, UA
dc.contributor.authorNEDDERMEYER, H
dc.contributor.authorNEUBER, M
dc.contributor.authorNEUMANN, M
dc.date.accessioned2021-12-23T16:08:34Z-
dc.date.available2021-12-23T16:08:34Z-
dc.date.issued1992
dc.identifier.issn00059021
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/8346-
dc.description.abstractWe have investigated the adsorption of CO and CO2 on epitaxially grown Cr2O3(111) by means of EELS, LEED, ARUPS, NEXAFS and XPS. CO is found to adsorb on the oxide surface in an ordered (square-root 3 x square-root 3)R30-degrees structure with the molecular axis oriented approximately parallel to the surface. CO2 on the other hand reacts with the chromium oxide to form a surface carbonate. Adsorption of CO, respectively reaction of CO2 only takes place on a clean. freshly flashed oxide surface. Preadsorption of oxygen leads to a surface which is rather inert to adsorption, likely due to electronic or steric reasons.
dc.language.isoen
dc.publisherVCH PUBLISHERS INC
dc.relation.ispartofBERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS
dc.subjectADSORPTION
dc.subjectALPHA-CHROMIA
dc.subjectANGLE-RESOLVED PHOTOEMISSION
dc.subjectChemistry
dc.subjectChemistry, Physical
dc.subjectMETHANOL
dc.subjectOXIDATION
dc.subjectOXYGEN-CHEMISORPTION
dc.subjectPHOTOELECTRON-SPECTROSCOPY XPS
dc.subjectPOLAR SURFACES
dc.subjectSINGLE-CRYSTAL SURFACES
dc.subjectSPECTROSCOPY, PHOTOELECTRON
dc.subjectSURFACES
dc.subjectTIO2(110)
dc.subjectZINC-OXIDE
dc.titleADSORPTION AND REACTION ON OXIDE SURFACES - CO AND CO2 ON CR2O3(111)
dc.typejournal article
dc.identifier.doi10.1002/bbpc.19920960104
dc.identifier.isiISI:A1992HD02100003
dc.description.volume96
dc.description.issue1
dc.description.startpage15
dc.description.endpage27
dc.contributor.orcid0000-0001-5188-852X
dc.contributor.researcheridAAQ-8810-2020
dc.publisher.place303 NW 12TH AVE, DEERFIELD BEACH, FL 33442-1788
dcterms.isPartOf.abbreviationBer. Bunsen-Ges. Phys. Chem. Chem. Phys.
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