Methyl 1-deoxy-1-(N-1-thyminyl)-beta-D-psicofuranoside
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Roivainen, Jarkko | |
dc.contributor.author | Reuter, Hans | |
dc.contributor.author | Mikhailopulo, Igor A. | |
dc.contributor.author | Eickmeier, Henning | |
dc.date.accessioned | 2021-12-23T16:11:16Z | - |
dc.date.available | 2021-12-23T16:11:16Z | - |
dc.date.issued | 2007 | |
dc.identifier.issn | 16005368 | |
dc.identifier.uri | https://osnascholar.ub.uni-osnabrueck.de/handle/unios/9613 | - |
dc.description.abstract | In the structure of the title compound, C12H18N2O7, the furanosyl ring adopts the S- type sugar pucker with the following pseudorotational parameters: P-S=159.6 degrees (C2 `-endo according to the designation of the ribofuranose ring of natural nucleosides; C3 `-endo according to the numbering of the title compound) and nu(max) = 35.9 degrees. The conformation around the C5 `-C6 ` bond is ap (gauche - trans; gt; -g), with a torsion angle gamma of -170.3 (2)degrees. The structure of the thymine base is very similar to that of thymidine. There are intermolecular N - H center dot center dot center dot O and O - H center dot center dot center dot O hydrogen bonds. | |
dc.language.iso | en | |
dc.publisher | BLACKWELL PUBLISHING | |
dc.relation.ispartof | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | |
dc.subject | CIRCULAR DICHROISM | |
dc.subject | Crystallography | |
dc.subject | DERIVATIVES | |
dc.subject | NUCLEOSIDES | |
dc.subject | THYMIDINE | |
dc.title | Methyl 1-deoxy-1-(N-1-thyminyl)-beta-D-psicofuranoside | |
dc.type | journal article | |
dc.identifier.doi | 10.1107/S1600536807048866 | |
dc.identifier.isi | ISI:000251281800285 | |
dc.description.volume | 63 | |
dc.description.issue | 11 | |
dc.description.startpage | O4294-U3155 | |
dc.contributor.researcherid | H-9847-2014 | |
dc.publisher.place | 9600 GARSINGTON RD, OXFORD OX4 2DQ, OXON, ENGLAND | |
dcterms.isPartOf.abbreviation | Acta Crystallogr. Sect. E.-Struct Rep. Online | |
crisitem.author.dept | Institut für Chemie neuer Materialien | - |
crisitem.author.deptid | institute11 | - |
crisitem.author.parentorg | FB 05 - Biologie/Chemie | - |
crisitem.author.grandparentorg | Universität Osnabrück | - |
crisitem.author.netid | ReHa636 | - |
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geprüft am 07.06.2024