van der Waals revisited

Autor(en): Baerwinkel, Klaus
Schnack, Juergen 
Stichwörter: fermion-boson symmetry; GASES; kinetic theory; Physics; Physics, Multidisciplinary; quasi-particle methods; van der Waals model
Erscheinungsdatum: 2008
Herausgeber: ELSEVIER SCIENCE BV
Journal: PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS
Volumen: 387
Ausgabe: 18
Startseite: 4581
Seitenende: 4588
Zusammenfassung: 
The van-der-Waals version of the second virial coefficient is not far from being exact if the model parameters are appropriately chosen. It is shown how the van-der-Waals resemblance originates from the interplay of thermal averaging and superposition of scattering phase shift contributions. The derivation of the two parameters from the quantum virial coefficient reveals a fermion-boson symmetry in non-ideal quantum gases. Numerical details are worked out for the Helium quantum gases. (C) 2008 Elsevier B.V. All rights reserved.
ISSN: 03784371
DOI: 10.1016/j.physa.2008.03.019

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