ALPHA-TETRAPHOSPHORUS TRICHALCOGENIDE DIIODIDE COMPOUNDS CONTAINING BOTH SULFUR AND SELENIUM

DC ElementWertSprache
dc.contributor.authorBLACHNIK, R
dc.contributor.authorLOENNECKE, P
dc.contributor.authorTATTERSHALL, BW
dc.date.accessioned2021-12-23T16:11:52Z-
dc.date.available2021-12-23T16:11:52Z-
dc.date.issued1992
dc.identifier.issn03009246
dc.identifier.urihttps://osnascholar.ub.uni-osnabrueck.de/handle/unios/9922-
dc.description.abstractTwo isomers of each of alpha-P4S2SeI2 and alpha-P4SSe2I2 have been identified by P-31 and Se-77 NMR spectroscopy in mixtures made by direct combination of the elements. The same compounds were formed as a result of a photochemical redistribution reaction between alpha-P4S3I2 and alpha-P4Se3I2 in solution in CS2. Systematic changes in chemical shifts and in coupling constants with alterations in molecular geometry, as sulfur was replaced by selenium in the series alpha-P4S3I2 1 - alpha-P4S2SeI2 2,3 - alpha-P4SSe2I2 4,5 - alpha-P4Se3I2 6, are reported.
dc.language.isoen
dc.publisherROYAL SOC CHEMISTRY
dc.relation.ispartofJOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
dc.subjectChemistry
dc.subjectChemistry, Inorganic & Nuclear
dc.subjectCONSTANTS
dc.subjectMAGNETIC-RESONANCE PARAMETERS
dc.subjectP-31
dc.subjectSPECTRA
dc.subjectTRISULFIDE SKELETON
dc.titleALPHA-TETRAPHOSPHORUS TRICHALCOGENIDE DIIODIDE COMPOUNDS CONTAINING BOTH SULFUR AND SELENIUM
dc.typejournal article
dc.identifier.doi10.1039/dt9920003105
dc.identifier.isiISI:A1992JY10600007
dc.description.issue21
dc.description.startpage3105
dc.description.endpage3109
dc.publisher.placeTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON ROAD, CAMBRIDGE, CAMBS, ENGLAND CB4 4WF
dcterms.isPartOf.abbreviationJ. Chem. Soc.-Dalton Trans.
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