Inner-shell excitation and fragmentation of sulfur aggregates
Autor(en): | Teodorescu, CM Gravel, D Choi, J Pugmire, D Dowben, PA Fominykh, N Pavlychev, AA Ruhl, E |
Stichwörter: | CLUSTERS; coincidence spectroscopy; COMPLEXES; extended Huckel calculations; inner-shell excitation; mass spectrometry; Spectroscopy; sulfur; VAPOR | Erscheinungsdatum: | 1999 | Herausgeber: | ELSEVIER SCIENCE BV | Enthalten in: | JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | Band: | 101 | Ausgabe: | SI | Startseite: | 193 | Seitenende: | 198 | Zusammenfassung: | Variable size sulfur aggregates (S-n with 3 less than or equal to n less than or equal to 8) were investigated in the S 2p excitation regime (160 eV less than or equal to E less than or equal to 175 eV) using monochromatic synchrotron radiation. Partial ion yields of mass-selected cations are compared with semiempirical extended Huckel calculations, yielding detailed information on the electronic and geometric structure of the aggregates. Inner-shell excitation in the S 2p regime leads to efficient formation of doubly charged species, which undergo rapid fragmentation via charge separation. The fragmentation pathways are investigated by photoelectron-photoion-photoion coincidence (PEPIPICO) spectroscopy. The charge separation mechanisms are interpreted in terms of Coulomb explosion. (C) 1999 Elsevier Science B.V. All rights reserved. |
Beschreibung: | 12th International Conference on Vacuum Ultraviolet Radiation Physics (VUV-12), SAN FRANCISCO, CA, AUG 03-07, 1998 |
ISSN: | 03682048 | DOI: | 10.1016/S0368-2048(98)00445-9 |
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geprüft am 06.06.2024