Notes on thermometric artefacts by Er3+ luminescence band interference

Autor(en): Ruehl, Philipp
Wang, Dongni
Garwe, Frank
Mueller, Robert
Haase, Markus 
Kraemer, Karl W.
Paa, Wolfgang
Heintzmann, Rainer
Heinemann, Stefan H.
Stafast, Herbert
Stichwörter: Frequency upconversion; Lanthanide ions; Luminescence band interference; NIR laser excitation; Optical thermometry; Optics
Erscheinungsdatum: 2021
Herausgeber: ELSEVIER
Journal: JOURNAL OF LUMINESCENCE
Volumen: 232
Zusammenfassung: 
Optical thermometry based on the intensity ratio of the H-2(11/2) -> I-4(15/2) (525 nm) and S-4(3/2) -> I-4(15/2) (545 nm) emission of Er3+ provides a powerful tool for microscale temperature sensing. Crystalline beta-NaYF4:Er,Yb is an excellent thermometry material for green upconversion emission upon NIR laser excitation. However, interfering H-2(9/2) -> I-4(13/2) emission is observed around 555 nm for continuous-wave laser excitation intensities above 10 W/cm(2). In this study, the green Er3+ emission bands are characterized and it is demonstrated how the true sample temperature is determined circumventing possible artefacts.
ISSN: 00222313
DOI: 10.1016/j.jlumin.2020.117860

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